Visible-light-driven 3D Bi5O7I/BiOCl microsphere with enhanced photocatalytic capability: Performance, degradation pathway, antibacterium and mechanism

Abstract

It is well known that both of the separation efficiency of photogenerated carriers and the response capability to visible light remarkably affect the photocatalytic performance. In the present work, a 3D microsphere of Bi₅O₇I/BiOCl heterojunction catalyst was synthetised. The synergy of Bi₅O₇I and BiOCl not only significantly enhances the transfer rate and separation efficiency of carriers, but also heightens light absorption capacity. As-prepared Bi₅O₇I/BiOCl (40 wt% BiOCl) has a higher degradation efficiency on doxycycline hydrochloride (DC) (90 min, 83.0%) and super high inhibition rate (90 min, 99.92%) on Escherichia coli under visible light, compared to the two monomers. Pollutants DC is finally decomposed into CO₂, H₂O and small molecule intermediates by generated h⁺, •OH and •O₂⁻. The effects of reactive radicals follow the order of •OH radicals > h⁺ radicals ≫ •O₂⁻ and e⁻ radicals. The possible structures of intermediates and four possible degradation pathways involved were also discussed. In addition, As-synthetised Bi₅O₇I/BiOCl has preferable reusability and excellent chemical stability. Biological toxicity experiments also verify that Bi₅O₇I/BiOCl is a green and environmentally friendly composite material. This strategy provides a green, low-toxic way for the application of traditional type II heterojunction in the fields of environmental remediation and photocatalysis.