H2S sensing under various humidity conditions with Ag nanoparticle functionalized Ti3C2Tx MXene field-effect transistors

Abstract

Despite the critical need to monitor H₂S, a hazardous gas, in environmental and medical settings, there are currently no reliable methods for rapid and sufficiently discriminative H₂S detection in real-world humid environments. Herein, targeted hybridizing of Ti₃C₂T_x MXene with Ag nanoparticles on a field-effect transistor (FET) platform has led to a step change in MXene sensing performance down to ppb levels, and enabled the very high selectivity and fast response/recovery time under room temperature for H₂S detection in humid conditions. For the first time, we present a novel relative humidity (RH) self-calibration strategy for the accurate detection of H₂S. This strategy can eliminate the influence of humidity and enables the accurate quantitative detection of gas in the total RH range. We further elucidate that the superior H₂S sensing performance is attributed to the electron and chemical sensitization effects. This study opens new avenues for the development of high-performance MXene-based sensors and offers a viable approach for addressing real-world humidity effect for gas sensors generally.