Preparation of metallic single-wall carbon nanotubes

IF 10.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Xiao-Qi Li , Peng-Xiang Hou , Chang Liu , Hui-Ming Cheng
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引用次数: 18

Abstract

Metallic single-wall carbon nanotubes (m-SWCNTs) have a high electrical conductivity due to ballistic electron transport, and have a bright future for use in nanocircuitry, conductive fibers, and transparent conductive films. To realize these applications, it is essential to obtain pure, high-quality m-SWCNTs on a large scale. In recent years, many techniques such as density-gradient centrifugation, gel chromatography, selective etching, direct growth by catalyst design and external electric field assistance have been developed to prepare m-SWCNTs. Here we present a state-of-the-art overview of the preparation of m-SWCNTs focusing on the principles, methods, and their advantages and limitations. The key challenges remaining for obtaining high quality m-SWCNTs with a high yield are discussed, and the developing trend for the selective preparation of m-SWCNTs is examined.

Abstract Image

金属单壁碳纳米管的制备
金属单壁碳纳米管(m-SWCNTs)由于具有弹道电子输运特性,具有很高的导电性,在纳米电路、导电纤维和透明导电膜等方面具有广阔的应用前景。为了实现这些应用,必须大规模获得纯净、高质量的m-SWCNTs。近年来,许多制备m-SWCNTs的技术如密度梯度离心、凝胶色谱、选择性蚀刻、催化剂设计直接生长和外电场辅助等都得到了发展。在这里,我们介绍了m-SWCNTs制备的最新概况,重点是原理、方法及其优点和局限性。讨论了制备高质量、高收率m-SWCNTs所面临的主要挑战,并展望了选择性制备m-SWCNTs的发展趋势。
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来源期刊
Carbon
Carbon 工程技术-材料科学:综合
CiteScore
20.80
自引率
7.30%
发文量
0
审稿时长
23 days
期刊介绍: The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.
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