Lab-based ambient pressure X-ray photoelectron spectroscopy from past to present

IF 8.2 1区化学 Q1 CHEMISTRY, PHYSICAL

Surface Science Reports Pub Date : 2018-05-01 DOI:10.1016/j.surfrep.2018.02.002

Chris Arble, Meng Jia, John T. Newberg

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引用次数: 50

Abstract

Chemical interactions which occur at a heterogeneous interface between a gas and substrate are critical in many technological and natural processes. Ambient pressure X-ray photoelectron spectroscopy (AP-XPS) is a powerful spectroscopy tool that is inherently surface sensitive, elemental and chemical specific, with the ability to probe sample surfaces in the presence of a gas phase. In this review, we discuss the evolution of lab-based AP-XPS instruments, from the first development by Siegbahn and coworkers up through modern day systems. A comprehensive overview is given of heterogeneous experiments investigated to date via lab-based AP-XPS along with the different instrumental metrics that affect the quality of sample probing. We conclude with a discussion of future directions for lab-based AP-XPS, highlighting the efficacy for this in-demand instrument to continue to expand in its ability to significantly advance our understanding of surface chemical processes under in situ conditions in a technologically multidisciplinary setting.

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从过去到现在的实验室环境压力x射线光电子能谱

发生在气体和基质之间的非均相界面上的化学相互作用在许多技术和自然过程中都是至关重要的。环境压力x射线光电子能谱(AP-XPS)是一种功能强大的光谱学工具，具有固有的表面敏感性，元素和化学特异性，能够探测存在气相的样品表面。在这篇综述中，我们讨论了基于实验室的AP-XPS仪器的演变，从Siegbahn和同事的第一次开发到现代系统。全面概述了迄今为止通过实验室AP-XPS研究的异质实验，以及影响样品探测质量的不同仪器指标。最后，我们讨论了基于实验室的AP-XPS的未来发展方向，强调了这种需求仪器的有效性，该仪器将继续扩展其能力，从而在多学科技术背景下显著推进我们对原位条件下表面化学过程的理解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Surface Science Reports 化学-物理：凝聚态物理

CiteScore

15.90

自引率

2.00%

发文量

审稿时长

178 days

期刊介绍： Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.