[Heated oils : analytical aspects].

R Guillaumin
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引用次数: 0

Abstract

About four hundred compounds from fatty acid molecule's clivage, oxidation and polymerisation have been isolated from heated fats. Because of this complexity, two steps of analysis will be considered: --an elaborate analysis: its aim is a best separation and characterisation of the components. It takes a long time and a great deal of means. Required for a basis knowledge, it is a guide for a control analysis; --a control analysis determinating the chemical compounds of a same family or with a similar structure. Thanks to specific methods oxiacids or oxidized glycerides and some cyclic-monomeres are determinated. The column chromatographies are able to separate unaltered compounds from the total polar artefacts, a gas chromatography with an internal standard is used for determing the cyclic monomeres. Heated fats and oils are also tested by a number of methods which involve identification of chemical and physical characteristics. Some examples are given.

[加热油:分析方面]。
从脂肪酸分子的裂解、氧化和聚合中分离出了大约400种化合物。由于这种复杂性,分析的两个步骤将被考虑:-一个详细的分析:其目的是最好的分离和表征的成分。这需要很长时间和大量的手段。需要有基础知识,它是控制分析的指南;——测定同一家族或具有相似结构的化合物的对照分析。由于特定的方法,可以测定氧化酸或氧化甘油酯和一些环单体。柱色谱法能够从总极性伪物中分离未改变的化合物,具有内标的气相色谱法用于测定环状单体。加热后的脂肪和油也可以用多种方法进行测试,这些方法包括化学和物理特性的鉴定。给出了一些例子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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