{"title":"Surface-coordinated metal-organic framework thin films (SURMOFs): From fabrication to energy applications","authors":"Yi-Hong Xiao , Yi-Bo Tian , Zhi-Gang Gu , Jian Zhang","doi":"10.1016/j.enchem.2021.100065","DOIUrl":null,"url":null,"abstract":"<div><p>The development of clean and sustainable energy is crucial to solve the increasingly serious energy crisis. Metal-organic frameworks (MOFs) containing both inorganic and organic components have attracted extensive attention on energy applications because of their tunable structures and fascinating properties. Particularly, liquid-phase epitaxial (LPE) layer by layer (LBL) growth of MOFs thin films on various substrates surfaces (called SURMOFs, surface-coordinated MOF thin films) possess the advantages of controlled thickness, preferred growth orientation and homogeneous film, which provide ideal candidates for energy storage and conversion. In this review, we summarize the fabrication strategies of SURMOFs including the layer by layer dipping, pump, spray, spin-coating and flowing methods, the classification and advantages of SURMOFs, and then discuss the related energy applications of SURMOFs, encapsulated SURMOFs, and SURMOF-derivative on electrocatalysis, photocatalysis, and solar cells <em>etc</em>.</p></div>","PeriodicalId":307,"journal":{"name":"EnergyChem","volume":"3 6","pages":"Article 100065"},"PeriodicalIF":22.2000,"publicationDate":"2021-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"17","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"EnergyChem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2589778021000154","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 17
Abstract
The development of clean and sustainable energy is crucial to solve the increasingly serious energy crisis. Metal-organic frameworks (MOFs) containing both inorganic and organic components have attracted extensive attention on energy applications because of their tunable structures and fascinating properties. Particularly, liquid-phase epitaxial (LPE) layer by layer (LBL) growth of MOFs thin films on various substrates surfaces (called SURMOFs, surface-coordinated MOF thin films) possess the advantages of controlled thickness, preferred growth orientation and homogeneous film, which provide ideal candidates for energy storage and conversion. In this review, we summarize the fabrication strategies of SURMOFs including the layer by layer dipping, pump, spray, spin-coating and flowing methods, the classification and advantages of SURMOFs, and then discuss the related energy applications of SURMOFs, encapsulated SURMOFs, and SURMOF-derivative on electrocatalysis, photocatalysis, and solar cells etc.
期刊介绍：
EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage
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