Engineering interactions between nanoparticles using polymers

IF 26 1区 化学 Q1 POLYMER SCIENCE
Huibin He , Xiaoxue Shen , Zhihong Nie
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引用次数: 5

Abstract

Nanoparticle assembly offers a versatile tool for constructing new structural materials with emergent or collective properties beyond individual nanoparticles. The achievement of desired properties and functions of these assembly materials often require delicate control over the interactions between nanoparticle building blocks. As of now, tremendous efforts have been devoted to manipulating the interparticle interactions by functionalizing the surface of nanoparticles with different ligands (e.g., small molecules, DNAs, proteins, and polymers). Among others, polymers are particularly attractive, owing to their tailorable molecular structures, rich functionalities, tunable responsiveness, superior biodegradability and biocompatibility, and easy mass production at low cost, etc. In this review, we present a summary of recent advances in engineering interparticle interactions between nanoparticles, especially inorganic nanoparticles with different sizes, shapes, and compositions, by tailoring the structurally defined polymers grafted or absorbed on the surface of nanoparticles. Discussions are focused on various interactions (i.e., steric repulsion, Coulombic interaction, hydrophobic interaction, hydrogen bonding, chemical reaction-induced recognitive interaction, and entropic effect) dominating the assembly of polymer-modified nanoparticles. Furthermore, the effect of external fields (e.g., light field, electric field, etc.) on the interactions between polymer-modified nanoparticles is presented.

Abstract Image

利用聚合物设计纳米颗粒之间的相互作用
纳米粒子组装提供了一种多功能的工具,用于构建具有紧急或集体特性的新结构材料,而不仅仅是单个纳米粒子。要实现这些组装材料所需的性能和功能,通常需要对纳米颗粒构建块之间的相互作用进行精细控制。到目前为止,人们已经做出了巨大的努力,通过用不同的配体(如小分子、dna、蛋白质和聚合物)功能化纳米颗粒的表面来操纵粒子间的相互作用。其中,聚合物因其具有可定制的分子结构、丰富的功能、可调节的响应性、优越的生物降解性和生物相容性以及易于低成本批量生产等特点,尤其具有吸引力。在这篇综述中,我们总结了近年来通过在纳米颗粒表面接枝或吸收结构明确的聚合物来修饰纳米颗粒,特别是不同尺寸、形状和成分的无机纳米颗粒之间的工程相互作用的进展。讨论的重点是各种相互作用(即,空间排斥,库仑相互作用,疏水相互作用,氢键,化学反应诱导的识别相互作用,熵效应)主导聚合物修饰纳米颗粒的组装。此外,还研究了外加场(如光场、电场等)对聚合物修饰纳米粒子相互作用的影响。
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来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
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