{"title":"Design and construction strategies to improve covalent organic frameworks photocatalyst's performance for degradation of organic pollutants","authors":"Si-Yu Hu, Yue-Na Sun, Zhi-Wen Feng, Fei-Ou Wang, Yun-kai Lv","doi":"10.1016/j.chemosphere.2021.131646","DOIUrl":null,"url":null,"abstract":"<div><p><span>Covalent organic frameworks (COFs) are a class of crystalline porous organic polymers. In recent years, COFs have received extensive attention in the field of photocatalytic degradation due to their large specific surface area, good thermal and solvent stability, and diverse structures. This review studies the progress of COF in the field of photocatalytic degradation, and summarizes the strategies to improve the photocatalytic activity of covalent organic frameworks, including the designs of ligands and structures. In particular, the design and construction of the COF composites (COF/MOF, COF/g-C</span><sub>3</sub>N<sub>4</sub>, COF/metal semiconductor) are discussed. The photocatalytic mechanism is described in detail, and the prospect of COFs in photocatalytic degradation is prospected.</p></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":null,"pages":null},"PeriodicalIF":8.1000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"31","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemosphere","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0045653521021184","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 31
Abstract
Covalent organic frameworks (COFs) are a class of crystalline porous organic polymers. In recent years, COFs have received extensive attention in the field of photocatalytic degradation due to their large specific surface area, good thermal and solvent stability, and diverse structures. This review studies the progress of COF in the field of photocatalytic degradation, and summarizes the strategies to improve the photocatalytic activity of covalent organic frameworks, including the designs of ligands and structures. In particular, the design and construction of the COF composites (COF/MOF, COF/g-C3N4, COF/metal semiconductor) are discussed. The photocatalytic mechanism is described in detail, and the prospect of COFs in photocatalytic degradation is prospected.
期刊介绍：
Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.
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