{"title":"Hydrogen-Bonded Supramolecular Liquid Crystals with Integrated Aggregation-Induced Emission and Room-Temperature Phosphorescence","authors":"Shan Li,Yudong Cao,Yunle Lu,Smruti Ranjan Sahoo,Qingli Li,Xinyan Gu,Glib Baryshnikov,Danfeng Ye,Liangliang Zhu","doi":"10.1039/d6cc05916c","DOIUrl":null,"url":null,"abstract":"A supramolecular hydrogen-bonding strategy converts a twisted non-mesogenic AIE luminogen into ordered smectic liquid crystals. The hydrogen-bond network acts as a conformation lock, planarizing excited states, enhancing intersystem crossing by two orders of magnitude, and activating room-temperature phosphorescence with an 8 ms lifetime.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"8 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2026-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d6cc05916c","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A supramolecular hydrogen-bonding strategy converts a twisted non-mesogenic AIE luminogen into ordered smectic liquid crystals. The hydrogen-bond network acts as a conformation lock, planarizing excited states, enhancing intersystem crossing by two orders of magnitude, and activating room-temperature phosphorescence with an 8 ms lifetime.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.