MBWCT-Net: Multiscale Transient Learning for Early Discrimination of Wood-Extracted VOC Mixtures via an Electronic Nose

IF 10.9 1区 化学 Q1 CHEMISTRY, ANALYTICAL
Qiuhong Zhang,Jinlin Liu,Xiuguo Zou,Yan Qian,Steven W. Su,Wentian Zhang,Maiken Ueland,Kainat Fatima,Taoping Liu,Shari L. Forbes
{"title":"MBWCT-Net: Multiscale Transient Learning for Early Discrimination of Wood-Extracted VOC Mixtures via an Electronic Nose","authors":"Qiuhong Zhang,Jinlin Liu,Xiuguo Zou,Yan Qian,Steven W. Su,Wentian Zhang,Maiken Ueland,Kainat Fatima,Taoping Liu,Shari L. Forbes","doi":"10.1021/acssensors.6c02142","DOIUrl":null,"url":null,"abstract":"Metal oxide semiconductor electronic noses offer a compact and nondestructive method for volatile organic compound (VOC) analysis. However, reliable recognition of multicomponent mixtures remains challenging because of sensor cross-sensitivity, nonlinear adsorption–desorption dynamics, sensor drift, and long acquisition cycles. Eucalyptus, Rosewood, and Sandalwood essential oils were used as controlled plant-derived VOC benchmarks. Static-headspace gas chromatography–mass spectrometry showed partially shared constituents but distinct dominant headspace fingerprints: Eucalyptus was rich in eucalyptol and monoterpenes, Rosewood was linalool-dominant, and Sandalwood showed a substantially different and partly unresolved profile. The three samples therefore did not exhibit uniformly high compositional similarity. We developed MBWCT-Net, a physics-motivated Multi-Branch Wavelet CNN–Transformer Network that combines a Multi-Scale Wavelet Parallel Network, Lightweight Cross-Attention, and a Multi-Scale Adaptive Transformer to model multiscale response components, cross-band coupling, and local–global temporal dependencies. Under an identical five-fold protocol, MBWCT-Net achieved 95.37 ± 0.61% accuracy and 95.37 ± 0.66% weighted F1, outperforming both raw-input and wavelet-enhanced baselines. Using the first 45 s of the transient response, accuracy reached 94.61 ± 0.70%, within 0.76 percentage points of the complete 60 s response. Deployment on an RK3588 platform yielded a single-sample inference latency of 12.4 ± 0.8 ms and a memory footprint of 48.5 MB. These measurements characterize computational feasibility and do not represent the duration of the complete sensing cycle. Response plots from three independent measurements and normalization-shape checks assessed short-term repeatability and preprocessing effects. Quantitative high-dimensional feature metrics and measured-noise physical-validity analyses evaluated class separability and the preservation of temporal morphology, respectively.","PeriodicalId":24,"journal":{"name":"ACS Sensors","volume":"12 1","pages":""},"PeriodicalIF":10.9000,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Sensors","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acssensors.6c02142","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Metal oxide semiconductor electronic noses offer a compact and nondestructive method for volatile organic compound (VOC) analysis. However, reliable recognition of multicomponent mixtures remains challenging because of sensor cross-sensitivity, nonlinear adsorption–desorption dynamics, sensor drift, and long acquisition cycles. Eucalyptus, Rosewood, and Sandalwood essential oils were used as controlled plant-derived VOC benchmarks. Static-headspace gas chromatography–mass spectrometry showed partially shared constituents but distinct dominant headspace fingerprints: Eucalyptus was rich in eucalyptol and monoterpenes, Rosewood was linalool-dominant, and Sandalwood showed a substantially different and partly unresolved profile. The three samples therefore did not exhibit uniformly high compositional similarity. We developed MBWCT-Net, a physics-motivated Multi-Branch Wavelet CNN–Transformer Network that combines a Multi-Scale Wavelet Parallel Network, Lightweight Cross-Attention, and a Multi-Scale Adaptive Transformer to model multiscale response components, cross-band coupling, and local–global temporal dependencies. Under an identical five-fold protocol, MBWCT-Net achieved 95.37 ± 0.61% accuracy and 95.37 ± 0.66% weighted F1, outperforming both raw-input and wavelet-enhanced baselines. Using the first 45 s of the transient response, accuracy reached 94.61 ± 0.70%, within 0.76 percentage points of the complete 60 s response. Deployment on an RK3588 platform yielded a single-sample inference latency of 12.4 ± 0.8 ms and a memory footprint of 48.5 MB. These measurements characterize computational feasibility and do not represent the duration of the complete sensing cycle. Response plots from three independent measurements and normalization-shape checks assessed short-term repeatability and preprocessing effects. Quantitative high-dimensional feature metrics and measured-noise physical-validity analyses evaluated class separability and the preservation of temporal morphology, respectively.

Abstract Image

MBWCT-Net:基于电子鼻的多尺度瞬态学习早期识别木材提取VOC混合物
金属氧化物半导体电子鼻为挥发性有机化合物(VOC)分析提供了一种紧凑、无损的方法。然而,由于传感器交叉灵敏度、非线性吸附-解吸动力学、传感器漂移和采集周期长,对多组分混合物的可靠识别仍然具有挑战性。桉树、红木和檀香精油被用作受控的植物源VOC基准。静态顶空气相色谱-质谱分析显示,桉树中含有丰富的桉树酚和单萜,红木中含有芳樟醇,檀香中含有不同的芳樟醇,檀香中含有不同的芳樟醇。因此,这三个样品并没有表现出一致的高成分相似性。我们开发了MBWCT-Net,这是一个物理驱动的多分支小波cnn -变压器网络,它结合了多尺度小波并行网络、轻量级交叉注意和多尺度自适应变压器来模拟多尺度响应分量、跨频带耦合和局部-全局时间依赖性。在相同的五层协议下,MBWCT-Net的准确率为95.37±0.61%,加权F1为95.37±0.66%,优于原始输入基线和小波增强基线。使用前45秒的瞬态响应,精度达到94.61±0.70%,与完整的60秒响应误差在0.76个百分点以内。在RK3588平台上的部署产生了12.4±0.8 ms的单样本推断延迟和48.5 MB的内存占用。这些测量表征了计算可行性,但不代表完整感知周期的持续时间。来自三个独立测量和归一化形状检查的响应图评估了短期可重复性和预处理效果。定量的高维特征度量和测量噪声物理有效性分析分别评估了类可分离性和时间形态的保存。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
ACS Sensors
ACS Sensors Chemical Engineering-Bioengineering
CiteScore
14.50
自引率
3.40%
发文量
372
期刊介绍: ACS Sensors is a peer-reviewed research journal that focuses on the dissemination of new and original knowledge in the field of sensor science, particularly those that selectively sense chemical or biological species or processes. The journal covers a broad range of topics, including but not limited to biosensors, chemical sensors, gas sensors, intracellular sensors, single molecule sensors, cell chips, and microfluidic devices. It aims to publish articles that address conceptual advances in sensing technology applicable to various types of analytes or application papers that report on the use of existing sensing concepts in new ways or for new analytes.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书