Cascade Electrosynthesis of Aryl Imides and Sulfonimides From N2 via Integrated Nitrogen Fixation and C─N/S─N Bond Formation

IF 17.6 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Angewandte Chemie International Edition Pub Date : 2026-10-19 DOI:10.1002/anie.9766022

Weijian Yang,Jing-Ao Fan,Limei Tian,Zijian Zhao,Tinghao Wu,Dan-Dan Zhai,Zhang-Jie Shi,Chi Zhang,Ke Hu

引用次数: 0

Abstract

A one-pot cascade electrochemical strategy directly links N2 fixation with C─N/S─N bond formation. By suppressing ammonia formation, electrochemically generated Li3N is preserved as the cascade intermediate and intercepted by acyl/sulfonyl chlorides, enabling value-added imide and sulfonimide synthesis from N2.

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结合固氮和C─N/S─N键形成的氮气级联电合成芳基酰亚胺和磺酰亚胺

一锅级联电化学策略直接将N2固定与C─N/S─N键形成联系起来。通过抑制氨的形成，电化学生成的Li3N被保留为级联中间体，并被酰基/磺酰氯化物拦截，从而实现从N2合成增值亚胺和磺酰亚胺。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Angewandte Chemie International Edition 化学-化学综合

CiteScore

26.60

自引率

6.60%

发文量

3549

审稿时长

1.5 months

期刊介绍： Angewandte Chemie, a journal of the German Chemical Society (GDCh), maintains a leading position among scholarly journals in general chemistry with an impressive Impact Factor of 16.6 (2022 Journal Citation Reports, Clarivate, 2023). Published weekly in a reader-friendly format, it features new articles almost every day. Established in 1887, Angewandte Chemie is a prominent chemistry journal, offering a dynamic blend of Review-type articles, Highlights, Communications, and Research Articles on a weekly basis, making it unique in the field.