Lignosulfonates and 5-hydroxymethylfurfural (HMF) as Formaldehyde-Free Adhesion Promoters in Fiber-Reinforced Elastomer Products

IF 5.2 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Macromolecular Materials and Engineering Pub Date : 2026-10-14 DOI:10.1002/mame.70355

Florian U. Rausch, Frank Gähr, Michael R. Buchmeiser

引用次数: 0

Abstract

Due to the increasing health and regulatory scrutiny of resorcinol-formaldehyde-latex (RFL) adhesion promoter systems, there is a growing demand for sustainable high-performance alternatives for technical elastomer products. Lignosulfonate and 5-hydroxymethylfurfural (HMF) are promising renewable resource-derived raw materials which, due to their chemical structure, are considered potential components of new adhesion promoter systems. In this work, various lignosulfonate- and HMF-based adhesion promoter systems for cord impregnation were developed and investigated on polyester (PES) and polyamide (nylon 66). The results indicate that these lignosulfonate- and HMF-based adhesion promoters have potential as alternatives to conventional RFL systems by enabling the formation of adhesive layers between textile reinforcing fibers and elastomer matrices.

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木质素磺酸盐和5-羟甲基糠醛（HMF）在纤维增强弹性体产品中的无甲醛粘附促进剂

由于间苯二酚-甲醛-乳胶（RFL）粘合促进剂系统的健康和监管审查日益严格，对可持续高性能技术弹性体产品替代品的需求不断增长。木质素磺酸盐和5-羟甲基糠醛（HMF）是很有前途的可再生资源衍生原料，由于它们的化学结构，被认为是新型粘附促进剂体系的潜在组分。在这项工作中，开发了各种木质素磺酸盐和hmf基的粘附促进剂体系，并对其在聚酯（PES）和聚酰胺（尼龙66）上的浸渍进行了研究。结果表明，这些基于木质素磺酸盐和hmf的粘合促进剂具有替代传统RFL系统的潜力，可以在纺织品增强纤维和弹性体基质之间形成粘合层。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Macromolecular Materials and Engineering 工程技术-材料科学：综合

CiteScore

7.30

自引率

5.10%

发文量

328

审稿时长

1.6 months

期刊介绍： Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications. Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science. The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments. ISSN: 1438-7492 (print). 1439-2054 (online). Readership:Polymer scientists, chemists, physicists, materials scientists, engineers Abstracting and Indexing Information: CAS: Chemical Abstracts Service (ACS) CCR Database (Clarivate Analytics) Chemical Abstracts Service/SciFinder (ACS) Chemistry Server Reaction Center (Clarivate Analytics) ChemWeb (ChemIndustry.com) Chimica Database (Elsevier) COMPENDEX (Elsevier) Current Contents: Physical, Chemical & Earth Sciences (Clarivate Analytics) Directory of Open Access Journals (DOAJ) INSPEC (IET) Journal Citation Reports/Science Edition (Clarivate Analytics) Materials Science & Engineering Database (ProQuest) PASCAL Database (INIST/CNRS) Polymer Library (iSmithers RAPRA) Reaction Citation Index (Clarivate Analytics) Science Citation Index (Clarivate Analytics) Science Citation Index Expanded (Clarivate Analytics) SciTech Premium Collection (ProQuest) SCOPUS (Elsevier) Technology Collection (ProQuest) Web of Science (Clarivate Analytics)