Oxidation of aminofurazans to azofurazans with electrically generated alkali metal hypohalites

IF 1.6 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2026-10-17 DOI:10.1007/s11172-026-5098-8

B. V. Lyalin, D. F. Fadeev, A. B. Sheremetev

引用次数: 0

Abstract

Transformation of aminofurazans into azofurazans via anodic oxidation of amino group at the furazan ring was investigated. Azofurazans were obtained in high yields (to 99%) by electrolysis in an undivided cell in aqueous solutions of alkali metal halides with participation of electrochemically generated alkali metal hypohalites acting as redox mediators. The electrochemical method is environmentally friendly and the electrolyte can be recycled with no appreciable decrease in the efficiency of aminofurazan oxidation.

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用电生成的碱金属次盐将氨基脲脲氧化为偶氮脲

研究了呋喃唑环上的氨基通过阳极氧化转化为偶氮呋喃唑。在电解生成的碱金属次盐作为氧化还原介质的参与下，在碱金属卤化物水溶液中，在未分裂的电解槽中电解，获得了高收率（99%）的偶氮脲类化合物。电化学方法对环境友好，电解液可循环利用，对氨呋脲的氧化效率无明显影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.