Piotr Dulian, Olena Sachuk, Olena Kiziun, Liudmyla Kotynska, Valery Zazhigalov, Marta Żurek, Janusz Jaglarz, Witold Żukowski
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引用次数: 0
Abstract
This study explores the sustainable synthesis of zinc oxide (ZnO) from industrial waste and its application in removing water contaminants such as chloramphenicol (CAP), metronidazole (MNZ), and prometryn (PROM). ZnO synthesized from zinc production waste (ZnO(2)) exhibited competitive photocatalytic performance compared to commercial ZnO (ZnO(1)), achieving 79% CAP degradation (Kd = 0.53 × 10-2 min-1) and 72% MNZ degradation (Kd = 0.43 × 10-2 min-1) under UV light, while showing higher activity in PROM degradation (32% removal) due to its mesoporous structure. Although ZnO(2) had a slightly lower specific surface area (24.9 m2/g) and pore volume (0.26 cm3/g) than ZnO(1), it demonstrated significant environmental and economic benefits by repurposing industrial waste. Catalytic tests in ethanol oxidation revealed ZnO(2) required higher temperatures for full conversion but exhibited higher acetaldehyde selectivity (70%). These findings highlight the potential of waste-derived ZnO as a sustainable alternative for water treatment and catalytic processes, aligning with circular economy principles and reducing reliance on natural resources.
期刊介绍:
Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.