Recent Advances in Boryl Radical Chemistry: The Rise of Visible-Light-Mediated Lewis Base-Coordinated Borane Chemistry

IF 5.7 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2026-10-15 Epub Date: 2026-10-10 DOI:10.1002/cjoc.70671

Yu-Qi Miao, Xuenian Chen

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Abstract

Comprehensive Summary

Lewis base-coordinated borane is air-stable, easy to handle, and employed as a boryl radical precursor under both thermal and photochemical conditions. Over the past few decades, the traditional ionic hydroboration method has been complemented by significant developments in radical-based hydroboration protocols, enabling the synthesis of diverse, value-added organoboron compounds. In this review, we have endeavored to present the state of the art in visible-light-driven Lewis base-coordinated boryl radical-promoted hydroboration, borylation, and XAT (X = halogen, H, CN) reactions, with a discussion covering reaction types, mechanisms, trends, and the distinctions between photo-induced and thermal-induced processes. The review presents a comprehensive overview of this theme, which has sparked significant research interest.

Key Scientists

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硼基自由基化学的最新进展：可见光介导的路易斯碱配位硼烷化学的兴起

路易斯碱配位硼烷具有空气稳定性，易于处理，在热和光化学条件下均可作为硼基前体。在过去的几十年里，传统的离子硼氢化方法已经被基于自由基的硼氢化方案的重大发展所补充，使合成多样化，高附加值的有机硼化合物成为可能。在这篇综述中，我们努力介绍了可见光驱动的路易斯碱配位硼基自由基促进的硼氢化、硼酰化和XAT （X =卤素、H、CN）反应的最新进展，并讨论了反应类型、机制、趋势以及光诱导和热诱导过程的区别。这篇综述对这一主题进行了全面的概述，并引发了重大的研究兴趣。关键的科学家

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.