Kavita Vishwakarma, Mario Gonzalez, Quentin Smets, Luca Panarella, Fateme Yekefalah, Tom Schram, Oguzhan Orkut Okudur, Ben Kaczer
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引用次数: 0
Abstract
Two-dimensional (2D) semiconductors are sensitive to mechanical stress due to their atomic thickness, weak van der Waals interfaces, and ultra-high sensitivity to the surrounding dielectric environment. While the effects of in-plane strain in transition-metal dichalcogenides (TMDs) have been extensively studied, the influence of locally generated out-of-plane compressive stress—commonly introduced during fabrication, packaging, and 3D integration—remains largely unexplored. Here, we apply controlled GPa-level perpendicular stress to monolayer WS2 field-effect transistors (FETs) using a nanoindenter integrated with in situ electrical measurements. Vertical compression reduces the on-state current by up to ∼74.2%, with partial recovery after unloading. Finite element modeling and electro-mechanical TCAD simulations indicate that mobility degradation is dominated by stress-induced enhancement of WS2–oxide interfacial coupling rather than intrinsic band-structure modification. Photoluminescence and Raman spectroscopy reveal that the WS2 lattice remains intact and show ∼0.5% relaxation of intrinsic tensile strain. These results establish a quantitative framework for understanding vertical-stress-driven transport degradation and highlight out-of-plane compression as an emerging reliability challenge for 2D materials in future stacked and heterogeneous device architectures.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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