Vertical Compressive Stress in Fab-Integrated WS2 FETs: An In Situ Electrical and Nanoindentation-Based Study

IF 4.7 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC
ACS Applied Electronic Materials Pub Date : 2026-10-13 Epub Date: 2026-09-18 DOI:10.1021/acsaelm.6c00701
Kavita Vishwakarma, Mario Gonzalez, Quentin Smets, Luca Panarella, Fateme Yekefalah, Tom Schram, Oguzhan Orkut Okudur, Ben Kaczer
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引用次数: 0

Abstract

Two-dimensional (2D) semiconductors are sensitive to mechanical stress due to their atomic thickness, weak van der Waals interfaces, and ultra-high sensitivity to the surrounding dielectric environment. While the effects of in-plane strain in transition-metal dichalcogenides (TMDs) have been extensively studied, the influence of locally generated out-of-plane compressive stress—commonly introduced during fabrication, packaging, and 3D integration—remains largely unexplored. Here, we apply controlled GPa-level perpendicular stress to monolayer WS2 field-effect transistors (FETs) using a nanoindenter integrated with in situ electrical measurements. Vertical compression reduces the on-state current by up to ∼74.2%, with partial recovery after unloading. Finite element modeling and electro-mechanical TCAD simulations indicate that mobility degradation is dominated by stress-induced enhancement of WS2–oxide interfacial coupling rather than intrinsic band-structure modification. Photoluminescence and Raman spectroscopy reveal that the WS2 lattice remains intact and show ∼0.5% relaxation of intrinsic tensile strain. These results establish a quantitative framework for understanding vertical-stress-driven transport degradation and highlight out-of-plane compression as an emerging reliability challenge for 2D materials in future stacked and heterogeneous device architectures.

晶圆片集成WS2场效应管的垂直压应力:基于原位电和纳米压痕的研究
二维(2D)半导体由于其原子厚度、弱范德华界面和对周围介电环境的超高灵敏度而对机械应力敏感。虽然平面内应变对过渡金属二硫化物(TMDs)的影响已经得到了广泛的研究,但局部产生的平面外压应力(通常在制造、封装和3D集成过程中引入)的影响仍然很大程度上未被探索。在这里,我们使用集成了原位电测量的纳米压头对单层WS2场效应晶体管(fet)施加受控的gpa级垂直应力。垂直压缩可使导通电流降低高达74.2%,卸载后可部分恢复。有限元建模和机电TCAD仿真表明,应力诱导的ws2 -氧化物界面耦合增强主导了迁移率的降低,而不是固有的能带结构改变。光致发光和拉曼光谱显示WS2晶格保持完整,并显示出约0.5%的本征拉伸应变弛豫。这些结果为理解垂直应力驱动的输运退化建立了定量框架,并强调了平面外压缩是未来堆叠和异构器件架构中二维材料可靠性的新挑战。
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来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊介绍: ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric. Indexed/​Abstracted: Web of Science SCIE Scopus CAS INSPEC Portico
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