Role of Amide Connectivity on the Assembly and the Supramolecular Stereomutation of Truxenone Triamides

Abstract

Assemblies of C-and N-centered truxenone triamides show markedly different stereochemical robustness despite similar selfassembly characteristics. Only the N-centered analogue undergoes solvent-induced stereomutation, highlighting how subtle structural changes can reshape the energetic landscape of supramolecular assemblies and identifying amide connectivity as an important parameter in supramolecular helicity control. 2 | J. Name.,