Quantum Fast Forwarding of Non-Markovian Quantum Dynamics

IF 4.5 2区 化学 Q2 CHEMISTRY, PHYSICAL
Avin Seneviratne,Peter L. Walters,Fei Wang
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Abstract

In this work, we present a quantum algorithm for simulating non-Markovian quantum dynamics based on the Feynman–Vernon influence functional formalism, which provides an exact description of the dynamics of a quantum system linearly coupled to a harmonic bath. In condensed-phase environments, the bath correlation functions typically decay over time, allowing them to be truncated beyond a finite time scale and enabling an iterative propagation scheme. We implement the finite-memory propagator using a fast-forwarding algorithm that achieves constant circuit depth with respect to the number of propagation steps, while the nonunitary matrices are realized on quantum circuits using unitary dilation. We further exploit the structure of the unitary dilation to show that the additional circuit complexity introduced by the dilation scales polynomially with the number of dilation ancilla qubits, while the dominant computational cost arises from the implementation of the underlying 1-dilation. The algorithm is compared with classical benchmark calculations for the spin-boson model and shows close agreement. Together, these developments establish a quantum-circuit framework for fast forwarding non-Markovian dynamics and identify the principal computational bottlenecks that must be overcome to achieve quantum advantage.

Abstract Image

非马尔可夫量子动力学的量子快进
在这项工作中,我们提出了一种基于费曼-弗农影响泛函形式的模拟非马尔可夫量子动力学的量子算法,该算法提供了与谐波槽线性耦合的量子系统动力学的精确描述。在凝聚相环境中,槽相关函数通常会随着时间的推移而衰减,从而允许它们在有限时间尺度之外被截断,并实现迭代传播方案。我们使用快速转发算法实现有限记忆传播器,该算法相对于传播步数实现恒定的电路深度,而非酉矩阵在量子电路上使用酉扩张实现。我们进一步利用了单位扩张的结构,表明由扩张引入的额外电路复杂性与扩张辅助量子比特的数量呈多项式比例,而主要的计算成本来自底层1-扩张的实现。将该算法与经典的自旋玻色子模型的基准计算进行了比较,结果表明该算法与经典的自旋玻色子模型非常吻合。总之,这些发展为快速推进非马尔可夫动力学建立了量子电路框架,并确定了实现量子优势必须克服的主要计算瓶颈。
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来源期刊
The Journal of Physical Chemistry Letters
The Journal of Physical Chemistry Letters CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
9.60
自引率
7.00%
发文量
1519
审稿时长
1.6 months
期刊介绍: The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.
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