Synthesis of 2,3′-Azacorrole Dimer via Acid-Catalyzed Oxidative Coupling

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2026-09-30 DOI:10.1134/S1070363226603170

Guoru Chen, Zhonglan Wei, Guangyuan Luo, Xiaofang Li

引用次数: 0

Abstract

2,3′-Azacorrole dimer was synthesized via regioselective oxidative coupling of 10-azacorrole by p-chloranil in the presence of trifluoroacetic acid in moderate yield. The structures of all the products were characterized thoroughly by NMR and HRMS. The UV-Vis absorption spectra show obvious bathochromic shifts of both the Soret band and Q bands, along with a marked increase in the absorbance of the Q bands.

查看原文本刊更多论文

酸催化氧化偶联合成2,3 ' -氮杂咯二聚体

在三氟乙酸的存在下，以对氯胺为原料，以区域选择性氧化偶联的方式合成了2,3′-氮杂咯咯二聚体。所有产物的结构都通过NMR和HRMS进行了全面表征。紫外-可见吸收光谱显示Soret波段和Q波段有明显的色移，Q波段的吸光度明显增加。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.