Effect of Gamma Irradiation on the IR Spectra and Mechanical Properties of Composites Derived from Epoxy Resin and Silicon Oxide Nanoparticles

IF 0.7 4区 化学 Q4 SPECTROSCOPY
E. Yu. Bobkova, V. S. Vasil′eva, O. O. Gavrilenko, M. A. Ksenofontov, L. A. Salnikava, E. I. Pavalanski
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引用次数: 0

Abstract

Composites derived from epoxy resin modified with silicon oxide nanoparticles were studied by spectral and physical-mechanical methods. The effects of the percentage content of the filler and the dose of γ-radiation on the strength of these composites were analyzed. The best procedure for hardening the composites was established. The optimal physical and mechanical characteristics were achieved at 1 mass% filler content and radiation dose 50 kGy. The basic spectral criteria were established to characterize the change in the physical and chemical structure of the composites by the action of γ-radiation. The appearance of IR bands at 1710–1740 cm–1 and an increase in the intensity of these bands with increasing radiation dose can serve as spectral criteria for greater destruction of the polymer matrix.

γ辐照对环氧树脂和氧化硅纳米颗粒复合材料红外光谱和力学性能的影响
采用光谱学和物理力学方法研究了环氧树脂经纳米氧化硅改性后制备的复合材料。分析了填料含量和γ辐射剂量对复合材料强度的影响。确定了复合材料的最佳硬化工艺。当填料质量分数为1质量%,辐照剂量为50 kGy时,材料的物理力学性能达到最佳。建立了表征复合材料在γ辐射作用下理化结构变化的基本光谱判据。在1710-1740 cm-1的红外波段的出现,以及这些波段的强度随辐射剂量的增加而增加,可以作为聚合物基质更大破坏的光谱标准。
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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