Concentration-driven faceting of MgO polyhedra boosts glucose isomerization in water.

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2026-10-20 DOI:10.1039/d6dt02360f

Kaiyue Cheng, Lin Gan, Meiqi Zheng, Wenying Shi, Xianggui Kong, Mingfei Shao

引用次数: 0

Abstract

A sustainable synthesis of polyhedral MgO exposing [200] facets is developed by modulating the raw concentration without organic solvents. The optimized catalyst exhibited 90.8% fructose selectivity and a yield of 43.3% in aqueous glucose isomerization. This work highlights crystal facet engineering as a promising strategy for biomass conversion catalysis.

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浓度驱动的氧化镁多面体面化促进了葡萄糖在水中的异构化。

在没有有机溶剂的情况下，通过调节原料浓度，开发了多面体MgO暴露[200]面的可持续合成。优化后的催化剂对果糖的选择性为90.8%，葡萄糖异构化收率为43.3%。这项工作强调了晶体面工程作为一种有前途的生物质转化催化策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.