Simulation of the Heating of Microdispersed Gold and Silver Particles in Various Media

IF 0.3 Q4 METALLURGY & METALLURGICAL ENGINEERING
A. M. Amdur, S. A. Fedorov, L. A. Ivanova
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引用次数: 0

Abstract

The size distribution of gold and silver particles in ores of various types and technogenic formations has been studied using a scanning electron microscope. The Au particle sizes are found to be mainly in the range less than 1–2 μm. The Ag particle sizes are in the range less than 10 μm. For example, the main fraction of gold particles in copper–pyrite ore is 0.01–0.5 and 0.5–1.0 μm. The problem of heating an ensemble of dispersed gold and silver particles in various mineral media has been solved using numerical methods and the Matlab software package. A temperature gradient is shown to exist over the cross section of both solid and liquid dispersed metal particles in all media during the heating period. Consequently, Au and Ag droplets move in pores under the action of the thermocapillary effect. At a high gold and silver content, contact and subsequent merging of droplets (coagulation) is possible. At a low content, this is unlikely, as studies of silicate–carbonate ore have shown; this is confirmed experimentally.

微分散金银颗粒在不同介质中的加热模拟
用扫描电子显微镜研究了不同类型和不同成因的矿石中金银颗粒的粒度分布。Au的粒度主要在1 ~ 2 μm以下。Ag的粒径在10 μm以下。例如,铜黄铁矿中金的主要粒度为0.01 ~ 0.5 μm和0.5 ~ 1.0 μm。利用数值方法和Matlab软件包,解决了不同矿物介质中分散的金银颗粒系综的加热问题。在加热过程中,所有介质中固体和液体分散金属颗粒的截面上都存在温度梯度。因此,在热毛细效应的作用下,Au和Ag液滴在孔隙中移动。在金和银含量高的情况下,液滴的接触和随后的合并(凝固)是可能的。在低含量的情况下,这是不可能的,正如对硅酸盐-碳酸盐矿石的研究所表明的那样;实验证实了这一点。
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来源期刊
Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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