{"title":"Barbier Polymerization-Induced Emission toward Organophosphorus-Containing Clusteroluminescent Polymer with Aggregation-Induced Emission and Photochromic Characteristics","authors":"Hong-Min Du, Xi-Yao Gu, Wen-Ming Wan, Xiao-Li Sun","doi":"10.1021/acsmacrolett.6c00424","DOIUrl":null,"url":null,"abstract":"<p>Stimuli-responsive\r\nluminescent polymers hold great promise for\r\nsmart materials, which, however, suffer from complicated synthetic\r\nprocedures involving synthesis of stimuli-responsive moiety, luminescent\r\nmoiety and the polymer mainchain separately. Herein, we report a one-pot\r\nBarbier polymerization-induced emission strategy to fabricate a stimuli-responsive\r\nclusteroluminescent organophosphorus-containing polymer with intriguing\r\naggregation-induced emission and photochromic characteristics, involving\r\nsynchronous C–C and C–P bonds formation. An efficient\r\npolymeric ligand for a nickel-catalyzed Kumada reaction and stimuli-responsive\r\npigment applications are demonstrated as well. This work therefore\r\nprovides a versatile strategy for the design of a stimuli-responsive\r\nclusteroluminescent polymer.</p>","PeriodicalId":18,"journal":{"name":"ACS Macro Letters","volume":"15 10","pages":"1538–1543"},"PeriodicalIF":4.9000,"publicationDate":"2026-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Macro Letters","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsmacrolett.6c00424","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2026/10/1 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Stimuli-responsive
luminescent polymers hold great promise for
smart materials, which, however, suffer from complicated synthetic
procedures involving synthesis of stimuli-responsive moiety, luminescent
moiety and the polymer mainchain separately. Herein, we report a one-pot
Barbier polymerization-induced emission strategy to fabricate a stimuli-responsive
clusteroluminescent organophosphorus-containing polymer with intriguing
aggregation-induced emission and photochromic characteristics, involving
synchronous C–C and C–P bonds formation. An efficient
polymeric ligand for a nickel-catalyzed Kumada reaction and stimuli-responsive
pigment applications are demonstrated as well. This work therefore
provides a versatile strategy for the design of a stimuli-responsive
clusteroluminescent polymer.
期刊介绍：
ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials, energy generation and storage, and renewable/sustainable materials. Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study. The scope of the journal includes high-impact research of broad interest in all areas of polymer science and engineering, including cross-disciplinary research that interfaces with polymer science.
With the launch of ACS Macro Letters, all Communications that were formerly published in Macromolecules and Biomacromolecules will be published as Letters in ACS Macro Letters.
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