Kang-Min Hu,Myung-Hyun Sohn,Yong-Su Kim,Kwang Jo Lee,Hyun Woo Kim,Hyang-Tag Lim
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引用次数: 0
Abstract
Abstract Accurate excited-state energies are essential for interpreting fluorescence and photochemical processes, yet variational quantum eigensolvers (VQEs) on noisy intermediate-scale quantum (NISQ) hardware have largely been confined to ground states. Subspace-search VQE (SSVQE) offers a NISQ-friendly route to excited states without ancilla-based overlap measurements, however it has lacked an experimental demonstration since it requires the coherent preparation and manipulation of multiple orthogonal basis states under a shared variational unitary. Here we realize SSVQE on a photonic platform by encoding orthogonal qudit states in the orbital angular momentum of single photons and optimizing a shared variational circuit. We estimate excited-state energies for a four-dimensional HeH + molecule and an eight-dimensional Heisenberg chain, thereby demonstrating scalable excited state eigensolving in a high-dimensional Hilbert space. Our results establish photonic qudits as a resource-efficient pathway to excited-state quantum simulation.
期刊介绍:
The scope of npj Quantum Information spans across all relevant disciplines, fields, approaches and levels and so considers outstanding work ranging from fundamental research to applications and technologies.