Shear-driven dynamics of surfactant-laden droplets on rough substrates

Abstract

The depinning of liquid droplets due to flow of a surrounding immiscible fluid plays a crucial role in applications such as enhanced oil recovery, surface cleaning, and crossflow emulsification. Although surfactants are often present in these systems, the role of Marangoni stresses on droplet depinning by an external flow remains unclear. To address this, we develop a lubrication-theory-based model for a thin Newtonian droplet laden with insoluble surfactant on a substrate with Gaussian-shaped defects which are used to account for the effects of surface roughness. The droplet is surrounded by a surfactant-free immiscible Newtonian fluid in a long, narrow rectangular channel, with flow driven by an applied pressure gradient. Using a precursor-film/disjoining-pressure approach for contact-line motion, we derive nonlinear evolution equations for the droplet thickness and interfacial surfactant concentration, which are solved numerically. The pressure gradient transports surfactant from the receding to the advancing contact line, generating a Marangoni flow opposing the pressure-driven flow. This reduces the net shear force on the droplet, leading to depinning at a higher critical pressure gradient. These findings reveal a previously unexamined regime in which interfacial Marangoni stresses, rather than uniform interfacial-tension reduction, govern the critical flow rate. The results provide a mechanistic basis for using surfactant-concentration gradients as a tunable handle to control droplet motion on rough substrates.