A core-level electron spectroscopy study of gas-phase 1,2,3-benzotriazole and methyl derivatives.

IF 3.5 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Beilstein Journal of Nanotechnology Pub Date : 2026-09-18 eCollection Date: 2026-01-01 DOI:10.3762/bjnano.17.88
Sven Bölke, Christophe Nicolas, John Bozek, Heiko Peisert, David R Batchelor
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引用次数: 0

Abstract

A gas-phase photoelectron spectroscopy and X-ray absorption spectroscopy study of 1,2,3-benzotriazole and methyl derivatives was undertaken to investigate the influence of the tautomerism on the spectroscopic signature in greater detail. Soft X-ray photoelectron spectroscopy of the nitrogen core level, nitrogen K-edge near-edge X-ray absorption fine-structure measurements, and mapping of the resonant Auger spectroscopy were performed. High-energy ultraviolet photoemission spectroscopy was also undertaken to compare with the previous studies using low-energy low-energy Helium I and Helium II excitation. The gas-phase characterization is an essential step for interpreting adsorbed molecular phases and thin films on surfaces. The results also served as a test of STOBE density functional theory calculations, in particular the near edge.

气相1,2,3-苯并三唑及其甲基衍生物的核能级电子能谱研究。
对1,2,3-苯并三唑及其甲基衍生物进行气相光电子能谱和x射线吸收能谱研究,更详细地研究了互变异构对光谱特征的影响。进行了氮核能级的软x射线光电子能谱、氮k边近边x射线吸收精细结构测量和共振俄歇能谱作图。我们还进行了高能紫外光发射光谱,与以往利用低能低能氦I和氦II激发的研究进行了比较。气相表征是解释表面吸附分子相和薄膜的重要步骤。结果也可以作为STOBE密度泛函理论计算的测试,特别是近边。
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来源期刊
Beilstein Journal of Nanotechnology
Beilstein Journal of Nanotechnology NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.70
自引率
3.20%
发文量
109
审稿时长
2 months
期刊介绍: The Beilstein Journal of Nanotechnology is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in nanoscience and nanotechnology. The journal is published and completely funded by the Beilstein-Institut, a non-profit foundation located in Frankfurt am Main, Germany. The editor-in-chief is Professor Thomas Schimmel – Karlsruhe Institute of Technology. He is supported by more than 20 associate editors who are responsible for a particular subject area within the scope of the journal.
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