{"title":"Endogenous Overdrive Stabilization in Monolithic One-Transistor-One-Electrolyte-Gated Transistor Devices for Mitigating Nonlinear Synaptic Updates","authors":"Shaoming Fu, Zhijie Lin, Shan Hu, Sixin Chen, Jiahui Lin, Peicheng Jiao, Yanghui Liu, Chuan Liu, Xiaoci Liang","doi":"10.1021/acsaelm.6c01515","DOIUrl":null,"url":null,"abstract":"<p>Solid-state electrolyte-gated transistors (EGTs) enable synaptic state updates for neuromorphic computing. When integrated with a driving transistor, the effective programming voltage is expected, under an idealized low-impedance model, to decrease as the conductance of EGT increases, leading to nonlinear synaptic update. Here, we show that this assumption does not hold in a CMOS-compatible 1T1E architecture that monolithically integrates a silicon NMOS with a LiPON-based EGT. In situ measurements reveal the opposite trend, where the effective programming voltage increases during pulsed operation. This behavior arises from electrolyte-dominated impedance evolution, which drives voltage redistribution and compensates the evolving electrochemical barrier. This endogenous stabilization of the electrochemical overdrive mitigates nonlinear synaptic update, enabling improved linearity and stable multilevel conductance modulation. These results indicate a regime-dependent framework in which programming dynamics are governed by impedance hierarchy rather than fixed biasing conditions.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":"8 18","pages":"8157–8166"},"PeriodicalIF":4.7000,"publicationDate":"2026-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsaelm.6c01515","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2026/9/9 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Solid-state electrolyte-gated transistors (EGTs) enable synaptic state updates for neuromorphic computing. When integrated with a driving transistor, the effective programming voltage is expected, under an idealized low-impedance model, to decrease as the conductance of EGT increases, leading to nonlinear synaptic update. Here, we show that this assumption does not hold in a CMOS-compatible 1T1E architecture that monolithically integrates a silicon NMOS with a LiPON-based EGT. In situ measurements reveal the opposite trend, where the effective programming voltage increases during pulsed operation. This behavior arises from electrolyte-dominated impedance evolution, which drives voltage redistribution and compensates the evolving electrochemical barrier. This endogenous stabilization of the electrochemical overdrive mitigates nonlinear synaptic update, enabling improved linearity and stable multilevel conductance modulation. These results indicate a regime-dependent framework in which programming dynamics are governed by impedance hierarchy rather than fixed biasing conditions.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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