Tetraphenylthiophene Derivatives With Strong Aggregation-Induced Electrochemiluminescence for Sensitive Detection of O,O-Dimethyl-O-2,2-dichlorovinylphosphate
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引用次数: 0
Abstract
Luminescence research is of great importance in electrochemiluminescence (ECL), particularly for organic luminophores with strong ECL signals. This study systematically investigated the ECL behaviors of tetraphenylthiophene (TPT) and its derivatives, which feature excellent electrical conductivity and high electron mobility. Notably, TPT-NH2 exhibited a robust ECL signal of approximately 17 000 a.u. with K2S2O8 as the co-reactant. This represents the first report of aggregation-induced electrochemiluminescence properties for this compound. Taking advantage of the strong oxidizing ability of K2S2O8, we constructed an ECL system using K2S2O8 as the “switch” and TPT-NH2 as the “lamp bulb”. This design enabled ultrasensitive detection of DDVP with a low limit of detection (LOD) of 1.74 nM.
期刊介绍：
Electroanalysis is an international, peer-reviewed journal covering all branches of electroanalytical chemistry, including both fundamental and application papers as well as reviews dealing with new electrochemical sensors and biosensors, nanobioelectronics devices, analytical voltammetry, potentiometry, new electrochemical detection schemes based on novel nanomaterials, fuel cells and biofuel cells, and important practical applications.
Serving as a vital communication link between the research labs and the field, Electroanalysis helps you to quickly adapt the latest innovations into practical clinical, environmental, food analysis, industrial and energy-related applications. Electroanalysis provides the most comprehensive coverage of the field and is the number one source for information on electroanalytical chemistry, electrochemical sensors and biosensors and fuel/biofuel cells.
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