En route towards "organic sodium": strongly excited-state reducing phenothiazines with application in photoredox catalysis.

IF 2.8 3区 化学 Q1 CHEMISTRY, ORGANIC
Carl J Rettig, Julia Steinfort, Tim Gathge, Robert Viehbeck, Philippe de Bary, Lena J Daumann, Thomas J J Müller, Klaus Schaper
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引用次数: 0

Abstract

The phenothiazine scaffold with a strongly electron-donating substituent is a suitable structural motif for the development of new photoredox catalysts operating in the oxidative quenching cycle. The design, investigation and application of new, highly reducing tri-substituted phenothiazines, which can be readily accessed in a one-pot procedure, reveal sodium-like oxidation potentials upon excitation with UV light.

在通往“有机钠”的道路上:强激发态还原吩噻嗪在光氧化还原催化中的应用。
具有强给电子取代基的吩噻嗪支架是开发在氧化猝灭循环中工作的新型光氧化还原催化剂的合适结构基序。新型高还原性三取代吩噻嗪的设计、研究和应用,在紫外光激发下揭示了钠样氧化电位,可以很容易地在一锅过程中获得。
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来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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