An electrochemical sensor based on a quaternary composite of HNb3O8 nanosheets/graphene/polyaniline/gold modified electrode to fast detection of dopamine and uric acid

IF 3.1 4区 化学 Q3 ELECTROCHEMISTRY
Yuge Liu, Guohua Zhou, Zhiguo Li, Yongmei Jia, Jing Chen
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引用次数: 0

Abstract

In this research, a material composed of HNb3O8 nanosheets, reduced graphene oxide (rGO), polyaniline (PANI) and gold nanoparticles (Au) was prepared and used for glassy carbon electrode (GCE) decoration. After modification, the electrode was then applied to detect dopamine (DA), as well as another biomolecular uric acid (UA). Optimal buffer pH values for individual determination were separately investigated. The sensor based on the modified GCE exhibited low detection limits in simultaneous detection, and the linear ranges were also wide. In individual detection, the detection limits were even lower. Meanwhile, the linear ranges also became wider. The sensor also demonstrated good anti-interference ability, repeatability, reproducibility. The stability was also long when detecting DA and UA. In practical sample detection, the results achieved by the sensor were satisfactory. This work not only provided new possible strategy for fast clinical detection of DA and UA but also found new application for composites of layered materials and graphene.

基于四元复合HNb3O8纳米片/石墨烯/聚苯胺/金修饰电极的电化学传感器快速检测多巴胺和尿酸
本研究制备了一种由HNb3O8纳米片、还原氧化石墨烯(rGO)、聚苯胺(PANI)和金纳米颗粒(Au)组成的材料,并将其用于玻璃碳电极(GCE)的装饰。修饰后,电极被用于检测多巴胺(DA),以及另一种生物分子尿酸(UA)。分别考察了单独测定缓冲液的最佳pH值。基于改进GCE的传感器同时检测限低,线性范围宽。在个体检测中,检出限甚至更低。同时,线性范围也变宽了。该传感器还表现出良好的抗干扰能力、重复性、再现性。在检测DA和UA时,稳定性也很长。在实际的样品检测中,该传感器取得了令人满意的结果。这项工作不仅为临床快速检测DA和UA提供了新的可能策略,而且为层状材料与石墨烯的复合材料提供了新的应用。
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来源期刊
CiteScore
4.80
自引率
4.00%
发文量
227
审稿时长
4.1 months
期刊介绍: The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry. The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces. The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis. The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.
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