Primary composition and evolution of kimberlite melts: A case study from the Chigicherla kimberlites with insights from autolith compositions

IF 1.9 4区 地球科学 Q3 GEOCHEMISTRY & GEOPHYSICS
Hero Kalra, Ashish Dongre
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引用次数: 0

Abstract

This study reports the first detailed characterization of an autolith embedded within the macrocrystic kimberlite CC-5 from the Chigicherla kimberlite cluster in the Wajrakarur Kimberlite Field (WKF), Southern India. These autoliths occur as large, globular, fine-grained fragments and are interpreted as early-crystallized kimberlite material. Their aphanitic texture is caused by undercooling during emplacement. The autolith phase is depleted in MgO (19.13 wt%) and SiO2 (21.41 wt%), moderately enriched in Al2O3 (3.36 wt%), TiO2 (3.79 wt%) and K2O (0.42 wt%), and shows notable concentrations of P2O5 (1.34 wt%), CaO (16.99 wt%) and FeOT (12.12 wt%). It is enriched in Light Rare Earth Elements (LREE) e.g., La, Ce, Nd, Sm and High Field Strength Elements (HFSE) such as Zr, Nb, Th and Ta. An attempt has been made to unravel the formation history of the autolith (aphanitic kimberlite), and to establish a compositional relationship with the host macrocrystic kimberlite. The major-element composition of the autolith suggests a slightly evolved melt relative to the primary kimberlite compositions. The evolutionary trends in primary kimberlite melts are further evaluated using fractionation and assimilation models. Lever-rule based compositional diagrams such as MgO versus SiO2, FeOT, and CaO indicate that ~ 30–35 wt% entrainment of bulk garnet lherzolite is required to reproduce the composition of the macrocrystic kimberlites, whereas up to ~ 45 wt% entrainment is needed for the olivine lamproites. These constraints suggest significant mantle wall-rock incorporation during melt ascent and evolution. Forward rare earth element modelling was conducted to estimate source compositions across 0.4–1.5% partial melting, assuming 2–5 vol% residual garnet in the mantle source. The resulting source composition aligns closely with the peridotite xenoliths from the Dharwar Craton, supporting derivation from a metasomatized sub-continental lithospheric mantle.

金伯利岩熔体的原始成分和演化:以奇奇切拉金伯利岩为例,从自溶岩成分中获得启示
本研究首次详细描述了印度南部Wajrakarur金伯利岩田(WKF) Chigicherla金伯利岩群中嵌入在大晶金伯利岩CC-5中的自砾岩。这些自石以大的、球状的、细粒的碎片出现,被解释为早期结晶的金伯利岩物质。它们的隐晶结构是由放置过程中的过冷引起的。自石相中MgO (19.13 wt%)和SiO2 (21.41 wt%)的含量较低,Al2O3 (3.36 wt%)、TiO2 (3.79 wt%)和K2O (0.42 wt%)的含量较低,P2O5 (1.34 wt%)、CaO (16.99 wt%)和FeOT (12.12 wt%)的含量较高。它富含La、Ce、Nd、Sm等轻稀土元素和Zr、Nb、Th、Ta等高场强元素。本文试图揭示该自长石(隐晶金伯利岩)的形成历史,并与寄主大晶金伯利岩建立成分关系。自长石的主要元素组成表明,相对于原始金伯利岩组成,熔体的演化程度较轻。利用分馏和同化模型进一步评价了原生金伯利岩熔体的演化趋势。基于杠杆规则的成分图,如MgO与SiO2、FeOT和CaO表明,要重现大晶金伯利岩的成分,需要块状石榴石-辉橄榄岩夹带~ 30-35 wt%,而橄榄石煌斑岩则需要高达45 wt%的夹带。这些限制条件表明,在熔融上升和演化过程中,地幔-岩石结合作用显著。假设地幔源中残留石榴石的比例为2-5 vol%,采用正演稀土元素模型估算了0.4-1.5%部分熔融的源成分。由此得到的烃源成分与Dharwar克拉通的橄榄岩包体密切一致,支持来自交代的次大陆岩石圈地幔。
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来源期刊
Mineralogy and Petrology
Mineralogy and Petrology 地学-地球化学与地球物理
CiteScore
2.60
自引率
0.00%
发文量
0
审稿时长
1 months
期刊介绍: Mineralogy and Petrology welcomes manuscripts from the classical fields of mineralogy, igneous and metamorphic petrology, geochemistry, crystallography, as well as their applications in academic experimentation and research, materials science and engineering, for technology, industry, environment, or society. The journal strongly promotes cross-fertilization among Earth-scientific and applied materials-oriented disciplines. Purely descriptive manuscripts on regional topics will not be considered. Mineralogy and Petrology was founded in 1872 by Gustav Tschermak as "Mineralogische und Petrographische Mittheilungen". It is one of Europe''s oldest geoscience journals. Former editors include outstanding names such as Gustav Tschermak, Friedrich Becke, Felix Machatschki, Josef Zemann, and Eugen F. Stumpfl.
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