Plasma gasification of agro-residues for syngas production: process optimization and system performance

Gitanjali Jothiprakash, Pugalendhi Sundararaju, Karthikeyan Subburamu, Sriramajayam Srinivasan, Paravaikkarasu Subramanian, Senthilarasu Sundaram, Ramesh Desikan
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Abstract

Syngas is one of the carbon-neutral biofuels derived from biomass through gasification that can replace fossil fuel usage. Plasma gasification performs better than conventional gasification in terms of syngas yield, quality, and the efficient cracking of heavy tar compounds. In this study, the performance evaluation of a direct current plasma torch-based gasifier (28 kW·h capacity) was tested using steam as a gasifying agent. The agro residues, viz., sunflower stalk, cashew nutshell, date palm husk, wheat straw, and tamarind pod, were chosen as feedstocks for plasma gasification. The temperature and flame length were selected as dependent variables to determine the gasification reaction, as temperature governs reaction kinetics and flame length indicates plasma heat distribution. The optimized plasma gasification conditions had three steam input ports in the plasma torch with 350 A and 20 V power inputs at a steam pressure of 150 kPa. Results revealed that the plasma gasifier showed higher efficiency (38.67%) with good syngas composition (%, volume fraction), averaging 22.27% carbon monoxide, 7.30% hydrogen, and 0.83% methane. The average specific syngas yield and higher heating value of the tested feedstock were 3.89±0.48 m3/kg and 3.95±0.30 MJ/m3, respectively. The plasma energy ratio of feedstock, energy closure, exergy efficiency, hot gas efficiency, and cold gas efficiency for the plasma gasifier correspond to average values for the tested agro residues and were found to be 0.10±0.01, 92.32%±4.71%, 29.68%±2.35%, 12.17%±0.75%, and 84.39%±5.57%, respectively. Syngas from agro residues through plasma gasification can be used to generate energy in prime movers such as internal combustion gas engines or gas turbines, owing to its favorable composition and heating value.

Graphical Abstract

用于合成气生产的农业残留物等离子气化:工艺优化和系统性能
合成气是一种碳中性生物燃料,通过气化从生物质中提取,可以取代化石燃料的使用。等离子气化在合成气产量、质量和重焦油化合物的有效裂解方面优于传统气化。本研究以蒸汽为气化剂,对容量为28 kW·h的直流等离子体火炬气化炉进行了性能评价试验。以向日葵秸秆、腰果壳、枣椰果壳、麦秸、罗望子豆荚为原料进行等离子气化。选择温度和火焰长度作为决定气化反应的因变量,因为温度决定反应动力学,火焰长度表示等离子体热分布。优化后的等离子体气化条件为:在蒸汽压力为150 kPa的条件下,等离子炬中有3个蒸汽输入口,输入功率为350 A、20 V。结果表明,等离子体气化炉效率较高(38.67%),合成气成分(%,体积分数)良好,平均一氧化碳22.27%,氢气7.30%,甲烷0.83%。试验原料的平均比合成气产率和较高热值分别为3.89±0.48 m3/kg和3.95±0.30 MJ/m3。等离子体气化炉的原料等离子体能量比、能量闭合度、火用效率、热气效率和冷气效率与所测农产品残渣的平均值基本一致,分别为0.10±0.01、92.32%±4.71%、29.68%±2.35%、12.17%±0.75%和84.39%±5.57%。由于其良好的成分和热值,通过等离子气化从农业残留物中提取的合成气可用于内燃机或燃气轮机等原动机中产生能量。图形抽象
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