Effect of Unmelted Nanoparticles on the High-Temperature Tribological Performance of YSZ Abradable Sealing Coatings

IF 3.4 3区 材料科学 Q2 MATERIALS SCIENCE, COATINGS & FILMS
Baixu Zhu, Wei Fan, Qi Liu, Zhicheng Yi, Yu Shi, Yi Zhang, Yu Bai
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Abstract

Yttria-stabilized zirconia (YSZ)-based abradable sealing coatings (ASCs) have attracted increasing attention in aero-engine sealing systems. However, their wear resistance at high temperatures remains a critical concern. In this work, two coatings with different unmelted nanoparticle contents (UNCs) were prepared by supersonic atmospheric plasma spraying (SAPS), and the influence of UNC on the high-temperature tribological performance of YSZ ASCs was systematically investigated. The microstructure, phase composition, and wear behavior of coatings were characterized using scanning electron microscopy, X-ray diffraction, and high-temperature tribological tests, respectively. The results showed that at a temperature of 1000 °C, changing the UNC significantly altered the friction coefficient and wear rate of the ASCs. For both coatings, wear behavior is primarily governed by abrasive wear, accompanied by extensive adhesion of wear debris. At elevated temperature, the unmelted nanoparticles act as weak regions within the coating. Under friction-induced shear stresses, they preferentially fragment and detach, which improves the abradability. These findings provide insights into the structural design of high-temperature ceramic-based ASCs.

未熔化纳米颗粒对YSZ耐磨密封涂层高温摩擦学性能的影响
钇稳定氧化锆(YSZ)基可磨密封涂层在航空发动机密封系统中越来越受到关注。然而,它们在高温下的耐磨性仍然是一个关键问题。采用超声速大气等离子喷涂(SAPS)技术制备了两种不同未熔化纳米颗粒(UNCs)含量的涂层,并系统研究了UNCs含量对YSZ ASCs高温摩擦学性能的影响。利用扫描电子显微镜、x射线衍射和高温摩擦学测试对涂层的微观结构、相组成和磨损性能进行了表征。结果表明,当温度为1000℃时,改变UNC可显著改变ASCs的摩擦系数和磨损率。对于这两种涂层,磨损行为主要是由磨料磨损控制的,伴随着磨损碎屑的广泛粘附。在升高的温度下,未熔化的纳米颗粒充当涂层内的薄弱区域。在摩擦引起的剪切应力下,它们优先破碎和分离,从而提高了耐磨性。这些发现为高温陶瓷ASCs的结构设计提供了见解。
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来源期刊
Journal of Thermal Spray Technology
Journal of Thermal Spray Technology 工程技术-材料科学:膜
CiteScore
5.20
自引率
25.80%
发文量
198
审稿时长
2.6 months
期刊介绍: From the scientific to the practical, stay on top of advances in this fast-growing coating technology with ASM International''s Journal of Thermal Spray Technology. Critically reviewed scientific papers and engineering articles combine the best of new research with the latest applications and problem solving. A service of the ASM Thermal Spray Society (TSS), the Journal of Thermal Spray Technology covers all fundamental and practical aspects of thermal spray science, including processes, feedstock manufacture, and testing and characterization. The journal contains worldwide coverage of the latest research, products, equipment and process developments, and includes technical note case studies from real-time applications and in-depth topical reviews.
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