Rhodopyran, a carboxylated hexahydrocyclopenta[b]pyran from Rhodococcus.

IF 2.7 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2026-07-28 eCollection Date: 2026-01-01 DOI:10.3762/bjoc.22.89

Enjuro Harunari, Sara Fushimi, Yasuhiro Igarashi

引用次数: 0

Abstract

A new bicyclic metabolite, rhodopyran (1), was isolated from the culture broth of Rhodococcus sp. strain RD066637. The planar structure was elucidated by 1D/2D NMR analyses and HRMS spectrometry, and the relative configuration was assigned from vicinal coupling constants and NOESY correlations, while the absolute configuration remains undetermined. Rhodopyran represents a structurally unusual carboxylated hexahydrocyclopenta[b]pyran and expands the known metabolite diversity of Rhodococcus, highlighting Rhodococcus as a source of uncommon natural-product scaffolds.

查看原文本刊更多论文

红双球菌，一种羧基化的六氢环五[b]吡喃。

从红球菌RD066637培养液中分离到一种新的双环代谢物红双环ran(1)。通过一维/二维核磁共振分析和HRMS谱分析对其平面结构进行了表征，并根据邻域耦合常数和NOESY相关性确定了相对构型，而绝对构型仍未确定。红双球菌是一种结构上不寻常的羧化六氢环五聚糖[b]吡喃，扩大了红双球菌已知代谢物的多样性，突出了红双球菌作为一种罕见的天然产物支架的来源。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.