Sensor Surfaces Based on Modified Silver Nanofilms for the Determination of Phosphates in Water by Surface-Enhanced Raman Scattering

IF 1.5 4区化学 Q4 CHEMISTRY, ANALYTICAL

Journal of Analytical Chemistry Pub Date : 2026-08-02 DOI:10.1134/S1061934826700528

I. K. Solontsov, M. V. Samodelova, O. O. Kapitanova, I. A. Veselova

引用次数: 0

Abstract

A sensitive approach to the determination of trace amounts of phosphate ions in aqueous solutions using surface-enhanced Raman spectroscopy on silver nanofilms modified with cetyltrimethylammonium bromide was proposed. The role of a surface modifier in enhancing the analytical signal was investigated. For pure sodium hydrogen phosphate solutions, the detection limit was 60 nM (5.7 μg/L), and the calibration function was linear over the hydrogen phosphate ion concentration range of 1 × 10^–7 to 1 × 10^–4 M.

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基于修饰银纳米膜的传感器表面增强拉曼散射法测定水中磷酸盐

提出了一种在十六烷基三甲基溴化铵修饰的银纳米膜上用表面增强拉曼光谱测定水溶液中痕量磷酸盐离子的灵敏方法。研究了表面改性剂对分析信号增强的作用。对于纯磷酸氢钠溶液，检出限为60 nM (5.7 μg/L)，在1 × 10-7 ~ 1 × 10-4 M的浓度范围内，校准函数呈线性关系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Analytical Chemistry 化学-分析化学

CiteScore

2.10

自引率

9.10%

发文量

146

审稿时长

13 months

期刊介绍： The Journal of Analytical Chemistry is an international peer reviewed journal that covers theoretical and applied aspects of analytical chemistry; it informs the reader about new achievements in analytical methods, instruments and reagents. Ample space is devoted to problems arising in the analysis of vital media such as water and air. Consideration is given to the detection and determination of metal ions, anions, and various organic substances. The journal welcomes manuscripts from all countries in the English or Russian language.