{"title":"Thermochemical Conversion of Apple Pomace into Engineered Biochar: Production, Properties, and Technological Applications","authors":"Josiel Martins Costa, Tânia Forster-Carneiro","doi":"10.1021/acsengineeringau.5c00107","DOIUrl":null,"url":null,"abstract":"<p>The engineering of\r\ncarbonaceous materials from agri-food residues\r\nhas become a promising strategy to advance sustainable materials,\r\nenergy technologies, and circular waste management. Apple pomace,\r\na high-volume byproduct of the juice industry, is an attractive feedstock\r\nfor biochar because of its high carbohydrate content and abundance\r\nof phenolic compounds. In this way, this perspective provides a comprehensive\r\nengineering analysis of apple pomace-derived biochar, focusing on\r\nhow feedstock characteristics, thermochemical conversion pathways,\r\nand reactor configurations govern the resulting structural, physicochemical,\r\nand functional properties. We synthesize recent advances in adsorption,\r\ncatalysis, soil conditioning, energy storage, and electrochemical\r\napplications, emphasizing structure–property–performance\r\nrelationships relevant to material design. Comparative analysis reveals\r\nthat pyrolysis temperature is the primary driver of surface area,\r\naromaticity, and functional group distribution, with high-temperature\r\nbiochar favoring electrochemical and catalytic applications, while\r\nlow-to-intermediate temperatures enhance adsorption and soil-related\r\nfunctionalities. Apple pomace–derived biochar exhibits competitive\r\nperformance relative to other agri-food byproducts, particularly in\r\nadsorption capacity and electrochemical activity, due to its oxygen-rich\r\nsurface chemistry and feedstock-specific mineral composition. Key\r\nlimitations, including variable feedstock quality, limited recyclability\r\nassessments, incomplete technoeconomic evaluations, and the lack of\r\nstandardized characterization protocols, are identified as constraints\r\nto scale-up and industrial deployment. Addressing these gaps is essential\r\nto position apple pomace biochar as an engineered material with the\r\npotential for integration into sustainable processes, low-carbon technologies,\r\nand circular bioeconomy frameworks.</p>","PeriodicalId":29804,"journal":{"name":"ACS Engineering Au","volume":"6 1","pages":"68–81"},"PeriodicalIF":9.0000,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Engineering Au","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsengineeringau.5c00107","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2026/1/22 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The engineering of
carbonaceous materials from agri-food residues
has become a promising strategy to advance sustainable materials,
energy technologies, and circular waste management. Apple pomace,
a high-volume byproduct of the juice industry, is an attractive feedstock
for biochar because of its high carbohydrate content and abundance
of phenolic compounds. In this way, this perspective provides a comprehensive
engineering analysis of apple pomace-derived biochar, focusing on
how feedstock characteristics, thermochemical conversion pathways,
and reactor configurations govern the resulting structural, physicochemical,
and functional properties. We synthesize recent advances in adsorption,
catalysis, soil conditioning, energy storage, and electrochemical
applications, emphasizing structure–property–performance
relationships relevant to material design. Comparative analysis reveals
that pyrolysis temperature is the primary driver of surface area,
aromaticity, and functional group distribution, with high-temperature
biochar favoring electrochemical and catalytic applications, while
low-to-intermediate temperatures enhance adsorption and soil-related
functionalities. Apple pomace–derived biochar exhibits competitive
performance relative to other agri-food byproducts, particularly in
adsorption capacity and electrochemical activity, due to its oxygen-rich
surface chemistry and feedstock-specific mineral composition. Key
limitations, including variable feedstock quality, limited recyclability
assessments, incomplete technoeconomic evaluations, and the lack of
standardized characterization protocols, are identified as constraints
to scale-up and industrial deployment. Addressing these gaps is essential
to position apple pomace biochar as an engineered material with the
potential for integration into sustainable processes, low-carbon technologies,
and circular bioeconomy frameworks.
期刊介绍:
)ACS Engineering Au is an open access journal that reports significant advances in chemical engineering applied chemistry and energy covering fundamentals processes and products. The journal's broad scope includes experimental theoretical mathematical computational chemical and physical research from academic and industrial settings. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Fundamental research in such areas as thermodynamics transport phenomena (flow mixing mass & heat transfer) chemical reaction kinetics and engineering catalysis separations interfacial phenomena and materialsProcess design development and intensification (e.g. process technologies for chemicals and materials synthesis and design methods process intensification multiphase reactors scale-up systems analysis process control data correlation schemes modeling machine learning Artificial Intelligence)Product research and development involving chemical and engineering aspects (e.g. catalysts plastics elastomers fibers adhesives coatings paper membranes lubricants ceramics aerosols fluidic devices intensified process equipment)Energy and fuels (e.g. pre-treatment processing and utilization of renewable energy resources; processing and utilization of fuels; properties and structure or molecular composition of both raw fuels and refined products; fuel cells hydrogen batteries; photochemical fuel and energy production; decarbonization; electrification; microwave; cavitation)Measurement techniques computational models and data on thermo-physical thermodynamic and transport properties of materials and phase equilibrium behaviorNew methods models and tools (e.g. real-time data analytics multi-scale models physics informed machine learning models machine learning enhanced physics-based models soft sensors high-performance computing)