Microstructural evolution and strengthening mechanism of Mg-Gd-Y-Zn-Zr alloy fabricated by wire arc additive manufacturing: Effects of heat treatment on mechanical properties

IF 9.6 1区 化学 Q1 CHEMISTRY, APPLIED
Journal of Rare Earths Pub Date : 2026-07-01 Epub Date: 2025-09-30 DOI:10.1016/j.jre.2025.09.046
Limin Zhang, Dongdong Zhang, Zizheng Zhang, Jiarui Hu, Ke Li, Yunlong Li, Liqin Wang, Zhanyong Zhao, Peikang Bai
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引用次数: 0

Abstract

Thin-walled Mg-8.5Gd-2.5Y-1.8Zn-0.5Zr (GWZ932) alloy component was successfully fabricated by the cold metal transfer (CMT) based wire-arc additive manufacturing (WAAM) process. Considering the significant influence of secondary phases on mechanical properties, we regulated the secondary phases through heat treatment. As-deposited sample exhibits the typical layered microstructure with alternating coarse/fine grains, along with a lot of Mg3(RE,Zn) eutectic phases at grain boundaries (GBs). After solid-solution treatment, these eutectic phases are transformed into coarse X phase at GBs and fine lamellar 14H long period ordered stacking (14H-LPSO) phases in grain interiors. Further peak-aging induces amounts of prismatic β′ phases precipitated in the α-Mg matrix, which produces the strong precipitation hardening effect. Note that prismatic β′ phases are perpendicular to basal 14H-LPSO phase in space, which can form a closed space that blocks dislocation motions more effectively. Thus, peak-aged sample exhibits a high tensile strength of (314 ± 3) MPa and an acceptable ductility of 4.3% ± 0.6%, which outperforms most Mg-Gd-Y series alloys prepared by WAAM reported previously. Our work provides a basis for forming thin-walled Mg-Gd-Y series components with high strength via WAAM process, but the deposition process should be further optimized.

Abstract Image

电弧增材制造Mg-Gd-Y-Zn-Zr合金的显微组织演变及强化机理:热处理对力学性能的影响
采用基于冷金属转移(CMT)的线弧增材制造(WAAM)工艺成功制备了Mg-8.5Gd-2.5Y-1.8Zn-0.5Zr (GWZ932)薄壁合金部件。考虑到二次相对力学性能的显著影响,我们通过热处理来调节二次相。沉积试样呈现出典型的粗/细交替层状微观结构,晶界处存在大量的Mg3(RE,Zn)共晶相。固溶处理后,这些共晶相转变为GBs处的粗X相和晶粒内部的14H长周期有序堆积(14H- lpso)细层状相。进一步峰时效使α-Mg基体中析出大量棱柱状β′相,产生强烈的析出硬化效应。柱状β′相在空间上垂直于基底14H-LPSO相,可以形成一个封闭空间,更有效地阻止位错运动。因此,峰时效样品的抗拉强度为(314±3)MPa,延展性为4.3%±0.6%,优于之前报道的大多数用WAAM制备的Mg-Gd-Y系列合金。本研究为采用WAAM工艺制备高强度Mg-Gd-Y系列薄壁部件提供了基础,但沉积工艺还需进一步优化。
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来源期刊
Journal of Rare Earths
Journal of Rare Earths 化学-应用化学
CiteScore
8.70
自引率
14.30%
发文量
374
审稿时长
1.7 months
期刊介绍: The Journal of Rare Earths reports studies on the 17 rare earth elements. It is a unique English-language learned journal that publishes works on various aspects of basic theory and applied science in the field of rare earths (RE). The journal accepts original high-quality original research papers and review articles with inventive content, and complete experimental data. It represents high academic standards and new progress in the RE field. Due to the advantage of abundant RE resources of China, the research on RE develops very actively, and papers on the latest progress in this field emerge every year. It is not only an important resource in which technicians publish and obtain their latest research results on RE, but also an important way of reflecting the updated progress in RE research field. The Journal of Rare Earths covers all research and application of RE rare earths including spectroscopy, luminescence and phosphors, rare earth catalysis, magnetism and magnetic materials, advanced rare earth materials, RE chemistry & hydrometallurgy, RE metallography & pyrometallurgy, RE new materials, RE solid state physics & solid state chemistry, rare earth applications, RE analysis & test, RE geology & ore dressing, etc.
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