Beyond Bibracte/Mont Beuvray: regional traditions and raw glass supply of red enamels in La Tène and Roman Central Europe

IF 2 2区 地球科学 Q1 ANTHROPOLOGY
Zuzana Zlámalová Cílová, Viktoria Čisťakova, Zdeněk Beneš, Šárka Matoušková, Petra Golaňová, Radoslav Čambal, Igor Bazovský, Gertruda Březinová, Maciej Karwowski, Hana Čižmářová, Josef Souček
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Abstract

This paper presents a compositional study of red enamels applied to metal artefacts from Central Europe, spanning the La Tène period (4th − 1st centuries BCE) to the Roman period (1st − 3rd centuries AD). The dataset comprises 107 enamel samples from Bohemia, Moravia, south-western Slovakia, Lower Austria and Styria, complemented by reference material (11 samples) from the oppidum of Bibracte/Mont Beuvray (France), the only site in Europe with direct archaeological evidence for enamel production in the La Tène period. Chemical compositions, including trace elements, were determined using LA-ICP-MS. All analysed enamels are soda–lime–silica glasses, frequently enriched in lead and copper. Based on K₂O and MgO contents, all La Tène enamels are natron-based, while Roman-period samples show greater compositional variability. Provenance assessment using Zr, Sr concentrations and trace-element ratios (Y₂O₃/ZrO₂ and CeO₂/ZrO₂) indicates that most Central European La Tène enamels differ from those produced at Bibracte/Mont Beuvray (France), reflecting distinct technological traditions and, in many cases, different sources of raw glass. Although Levantine natron glass dominates the assemblage, a smaller group of enamels – mainly dated to the Middle La Tène period – exhibits characteristics consistent with Egyptian glass. The results demonstrate both continuity in the use of lead- and copper-rich red enamels into the Roman period and significant changes in raw glass supply and decolourising practices. Overall, the study provides new insights into regional organisation of enamel production and long-distance glass circulation in Iron Age and Roman Central Europe.

超越Bibracte/Mont Beuvray: La t和罗马中欧的红色搪瓷的地区传统和原玻璃供应
本文介绍了一项用于中欧金属工艺品的红色搪瓷成分研究,涵盖了La t时期(公元前4 - 1世纪)到罗马时期(公元1 - 3世纪)。该数据集包括来自波西米亚、摩拉维亚、斯洛伐克西南部、下奥地利和施蒂利亚的107个珐琅样本,以及来自Bibracte/Mont Beuvray(法国)的oppidum的参考材料(11个样本),Bibracte/Mont Beuvray(法国)是欧洲唯一一个拥有La t时期珐琅生产直接考古证据的遗址。化学成分(包括微量元素)用LA-ICP-MS测定。所有被分析的珐琅都是钠-石灰-硅玻璃,通常富含铅和铜。根据K₂O和MgO含量,所有La t珐琅都是钠基的,而罗马时期的样品显示出更大的成分变化。使用Zr, Sr浓度和微量元素比率(Y₂O₃/ZrO₂和CeO₂/ZrO₂)进行的来源评估表明,大多数中欧La t珐琅不同于Bibracte/Mont Beuvray(法国)生产的珐琅,反映了不同的技术传统,在许多情况下,不同的原玻璃来源。尽管黎凡特钠碱玻璃占主导地位,但一小部分搪瓷(主要是La t中期)显示出与埃及玻璃一致的特征。结果表明,在罗马时期,使用富含铅和铜的红色搪瓷的连续性,以及原玻璃供应和脱色方法的重大变化。总的来说,这项研究为铁器时代和罗马中欧的珐琅生产和长途玻璃流通的区域组织提供了新的见解。
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来源期刊
Archaeological and Anthropological Sciences
Archaeological and Anthropological Sciences GEOSCIENCES, MULTIDISCIPLINARY-
CiteScore
4.80
自引率
18.20%
发文量
199
期刊介绍: Archaeological and Anthropological Sciences covers the full spectrum of natural scientific methods with an emphasis on the archaeological contexts and the questions being studied. It bridges the gap between archaeologists and natural scientists providing a forum to encourage the continued integration of scientific methodologies in archaeological research. Coverage in the journal includes: archaeology, geology/geophysical prospection, geoarchaeology, geochronology, palaeoanthropology, archaeozoology and archaeobotany, genetics and other biomolecules, material analysis and conservation science. The journal is endorsed by the German Society of Natural Scientific Archaeology and Archaeometry (GNAA), the Hellenic Society for Archaeometry (HSC), the Association of Italian Archaeometrists (AIAr) and the Society of Archaeological Sciences (SAS).
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