Carbon nanotubes/heteropoly acid-coated stainless steel mesh as a green heterogeneous catalyst in chromene synthesis

IF 3.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Sara Ghavidel, Ghasem Aghapour, Seyedeh Fatemeh Hojati
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引用次数: 0

Abstract

In the current work, stainless steel mesh was coated with a Keggin-type heteropoly acid (H3PW12O40) and carbon nanotubes (SSM/CNT/HPA) using the sol–gel process and characterized by FT-IR, FE-SEM, EDS, TGA, XRD, and BET analyses. This new heterogeneous nanocomposite was used to synthesize chromene derivatives via multi-component reaction. Easy separation of the catalyst from the reaction mixture by a pair of tweezers is the most important advantage of the current work and make it a unique choice for organic transformations. Furthermore, the designed catalyst had features such as high surface area, stability in the air and reaction medium, reusability without significant reduction in catalytic performance, and high efficiency in multi-component reactions.

Abstract Image

碳纳米管/杂多酸包覆不锈钢网在铬合成中的绿色非均相催化剂研究
采用溶胶-凝胶法对不锈钢网进行keggin型杂多酸(H3PW12O40)和碳纳米管(SSM/CNT/HPA)包覆,并通过FT-IR、FE-SEM、EDS、TGA、XRD和BET分析对其进行表征。该非均相纳米复合材料通过多组分反应合成了铬烯衍生物。用镊子从反应混合物中轻松分离催化剂是目前工作中最重要的优点,使其成为有机转化的独特选择。此外,所设计的催化剂具有比表面积大、在空气和反应介质中稳定、可重复使用而不显著降低催化性能、多组分反应效率高等特点。
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来源期刊
CiteScore
5.70
自引率
18.20%
发文量
229
审稿时长
2.6 months
期刊介绍: Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry. The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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