Z-Selective semihydrogenation of alkynes via Ni/Lewis acid synergistic catalyzed system using DMF as hydrogen source and solvent.

IF 2.7 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2026-06-30 eCollection Date: 2026-01-01 DOI:10.3762/bjoc.22.79

Lei Kang, Haifeng Gao, Luo Yang

引用次数: 0

Abstract

A Ni/Lewis acid dual-catalytic system has been developed for the Z-selective semihydrogenation of alkynes. Utilizing DMF as both the hydrogen donor and reaction medium, this method affords Z-alkenes in high yield with excellent stereoselectivity under mild conditions. The protocol employs cost-effective and readily available catalysts, and demonstrates broad applicability across a wide range of substrates.

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以DMF为氢源和溶剂，Ni/Lewis酸协同催化体系中炔的z选择性半加氢。

建立了一种Ni/Lewis酸双催化体系，用于炔的z选择性半加氢反应。该方法利用DMF作为给氢体和反应介质，在温和的条件下获得了高收率和良好的立体选择性的z -烯烃。该方案采用成本效益高且容易获得的催化剂，并证明了广泛的适用性，在广泛的底物范围内。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.