Ag-Containing Catalysts Based on CeO2–Fe2O3@SBA-15 for CO Oxidation

IF 0.7 4区 化学 Q4 CHEMISTRY, APPLIED
N. N. Mikheeva, G. V. Mamontov
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引用次数: 0

Abstract

A series of Ag-containing catalysts for CO oxidation based on CeO2–Fe2O3@SBA-15 composites synthesized by salt encapsulation in the hybrid material Pluronic-P123@SBA-15 was obtained. The effect of a block copolymer of polyethylene glycol and polypropylene glycol Pluronic-P123 inside the SBA-15 structure (ordered mesoporous silicon dioxide) on the distribution and dispersion of the deposited CeO2 and Fe2O3 components is shown. The deposition of cerium and iron oxides on Pluronic@SBA-15 makes it possible to stabilize CeO2 and Fe2O3 in the form of highly dispersed particles evenly distributed on the surface of the carrier. It was shown that the use of CeO2 and Fe2O3 stabilized in the SBA-15 structure makes it possible to increase the activity of Ag-containing catalysts in the CO oxidation reaction compared with the Ag/SBA-15 catalyst.

Abstract Image

基于CeO2 - Fe2O3@SBA-15的含银CO氧化催化剂
在杂化材料Pluronic-P123@SBA-15中采用盐包埋法制备了一系列以CeO2 - Fe2O3@SBA-15复合材料为基础的含银CO氧化催化剂。研究了SBA-15结构中聚乙二醇和聚丙烯乙二醇嵌段共聚物Pluronic-P123(有序介孔二氧化硅)对沉积的CeO2和Fe2O3组分分布和分散的影响。在Pluronic@SBA-15上沉积铈和铁氧化物,使得CeO2和Fe2O3以高度分散的颗粒形式均匀地分布在载体表面。结果表明,与Ag/SBA-15催化剂相比,在SBA-15结构中使用稳定的CeO2和Fe2O3可以提高含Ag催化剂在CO氧化反应中的活性。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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