{"title":"Watching catalysts work during CO2 hydrogenation","authors":"Gianfranco Pacchioni","doi":"10.1016/j.checat.2026.101760","DOIUrl":null,"url":null,"abstract":"In a recent issue of <ce:italic>Nature Catalysis</ce:italic>, Boniface et al. use <ce:italic>operando</ce:italic> techniques to gain new insights into how classical Cu/ZnO/Al<ce:inf loc=\"post\">2</ce:inf>O<ce:inf loc=\"post\">3</ce:inf> catalysts operate in methanol synthesis, significantly advancing our understanding of their behavior. These catalysts function as a dynamic ensemble of Cu, ZnO<ce:inf loc=\"post\"><ce:italic>x</ce:italic></ce:inf> ultrathin films, and Cu–Zn alloy phases that continuously interconvert under reaction conditions. However, the atomistic nature of the active site remains elusive.","PeriodicalId":53121,"journal":{"name":"Chem Catalysis","volume":"32 1","pages":""},"PeriodicalIF":10.7000,"publicationDate":"2026-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.checat.2026.101760","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In a recent issue of Nature Catalysis, Boniface et al. use operando techniques to gain new insights into how classical Cu/ZnO/Al2O3 catalysts operate in methanol synthesis, significantly advancing our understanding of their behavior. These catalysts function as a dynamic ensemble of Cu, ZnOx ultrathin films, and Cu–Zn alloy phases that continuously interconvert under reaction conditions. However, the atomistic nature of the active site remains elusive.
期刊介绍:
Chem Catalysis is a monthly journal that publishes innovative research on fundamental and applied catalysis, providing a platform for researchers across chemistry, chemical engineering, and related fields. It serves as a premier resource for scientists and engineers in academia and industry, covering heterogeneous, homogeneous, and biocatalysis. Emphasizing transformative methods and technologies, the journal aims to advance understanding, introduce novel catalysts, and connect fundamental insights to real-world applications for societal benefit.