Quantitative Evaluation of Organic Matter Enrichment of the Lower Cambrian Shale in Intraplatform Basins of the Yangtze Platform (South China): A Machine Learning Approach

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Earth and Space Chemistry Pub Date : 2026-06-18 Epub Date: 2026-05-27 DOI:10.1021/acsearthspacechem.6c00056
Wei Liu, Ping Gao*, Gary G. Lash, Jinku Li, Guangming Meng, Siyi Liu, Yijie Xing, Yanming Zhao, Dongsheng Li and Xianming Xiao, 
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Abstract

The Ediacaran-Cambrian transition marked a critical period in Earth’s history with dramatic marine environmental fluctuations. Shale successions in intraplatform basins preserve sedimentary records reflecting early Cambrian ocean evolution. However, differences in paleo-marine environments among Yangtze Block’s intraplatform basins and their controls on organic matter enrichment remain poorly constrained. This study presents a comparative geochemical analysis of the western Hubei–eastern Chongqing (EYIB) and Deyang–Anyue intraplatform basins (DAIB) based on data from 13 Lower Cambrian sections. Using machine learning integrated with explanation models, we quantitatively identified dominant factors controlling organic matter enrichment. During the early Cambrian, the Yangtze Block experienced climate shift from cool-arid to relatively warm-humid, with weathering transitioning from physical to chemical dominance. The DAIB received more terrigenous sediment than the EYIB despite similar sedimentation rates. Interval II deposits accumulated under largely anoxic conditions with intermittent euxinia, while Interval III records oxygenated conditions interrupted by anoxia episodes and reduced productivity. The EYIB evolved from moderate to strongly restricted hydrological conditions, with Interval II showing enhanced upwelling. Conversely, the DAIB remained highly restricted with minimal upwelling evidence during Interval III. Machine learning reveals preservation as the dominant control on organic matter enrichment in Interval II (49.4% contribution), followed by productivity (30.6%). Preservation importance increased during Interval III (52.5%), with sedimentation rate (20.6%) and terrigenous input (16.3%) becoming secondary factors. The early Cambrian organic-rich shales record complex interactions among paleoclimate fluctuation, environmental variation, and biological evolution, enhancing our understanding of oceanic evolution and organic carbon burial during this critical transition.

Abstract Image

扬子地台内盆地下寒武统页岩有机质富集定量评价:机器学习方法
埃迪卡拉-寒武纪的过渡标志着地球历史上海洋环境剧烈波动的关键时期。台内盆地的页岩序列保存了反映早寒武世海洋演化的沉积记录。然而,对扬子地块地内盆地古海相环境差异及其对有机质富集的控制作用仍知之甚少。基于13个下寒武统剖面资料,对鄂西渝东盆地(EYIB)和德阳安岳地台内盆地(DAIB)进行对比地球化学分析。利用机器学习与解释模型相结合的方法,我们定量地确定了控制有机质富集的主导因素。早寒武世,扬子地块经历了由冷干旱向相对温暖湿润的气候转变,风化作用由物理风化为主向化学风化为主转变。尽管沉积速率相似,但东洋盆地比东洋盆地吸收了更多的陆源沉积物。段II沉积物主要在缺氧条件下积累,间歇缺氧,而段III则记录了缺氧发作和生产力下降所中断的含氧条件。eib由中度限制水文条件向强限制水文条件演变,区间II表现为上升流增强。相反,在第III段,DAIB仍然受到高度限制,上升流的证据很少。机器学习显示,保存是对区间II有机质富集的主要控制因素(贡献49.4%),其次是生产力(贡献30.6%)。沉积速率(20.6%)和陆源输入(16.3%)成为次要因素。早寒武世富有机质页岩记录了古气候波动、环境变化和生物演化之间复杂的相互作用,增强了我们对这一关键转变时期海洋演化和有机碳埋藏的认识。
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来源期刊
ACS Earth and Space Chemistry
ACS Earth and Space Chemistry Earth and Planetary Sciences-Geochemistry and Petrology
CiteScore
5.30
自引率
11.80%
发文量
249
期刊介绍: The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.
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