Electroreductive Desulfurization of Thioacetals

IF 5.2 4区化学 Q2 ELECTROCHEMISTRY

ChemElectroChem Pub Date : 2026-06-07 DOI:10.1002/celc.70240

Ellymay Goossens, Pintu Maity, Caterina Momoli, Andrey Shatskiy, Johannes Röckl, Guillermo Ahumada, Laura Palombi, Helena Lundberg

引用次数: 0

Abstract

A metal-free electrochemical protocol for desulfurization of aryl thioacetals into alkanes under ambient conditions is reported. The method is fully selective for C(sp³)─S bond cleavage, serving as an electrochemical alternative to Mozingo reduction via intermediate formation of thioethers. With a switch of solvent, the transformation enables the formation of deuterated products.

Abstract Image

查看原文本刊更多论文

硫缩醛的电还原脱硫

报道了一种在环境条件下芳基硫缩醛脱除成烷烃的无金属电化学方案。该方法对C（sp3）─S键的裂解具有完全的选择性，可以作为通过中间形成硫醚的Mozingo还原的电化学替代方法。通过切换溶剂，这种转变可以形成氘化产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

ChemElectroChem ELECTROCHEMISTRY-

CiteScore

7.90

自引率

2.50%

发文量

515

审稿时长

1.2 months

期刊介绍： ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.