Tracking Dehydration Reactions and Fossil Fluid Flux in Shear Zones Using Garnet Microstructures

IF 3.4 2区 地球科学 Q1 GEOLOGY
Journal of Metamorphic Geology Pub Date : 2026-06-02 Epub Date: 2026-05-03 DOI:10.1111/jmg.70042
Alessandro Petroccia, Francesco Giuntoli, Alissa Kotowski, Gianmarco Buono, Alireza Chogani, Eric Hellebrand, Lucia Pappalardo, Ivan Callegari
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Abstract

Shear zones act as preferential fluid pathways during prograde and retrograde stages of metamorphism. Nonetheless, we still have limited knowledge of the drainage and permeability of natural settings. The preserved signature of fluid in exhumed rocks provides insights into fluid flow during burial and exhumation. This study investigates fluid flow processes recorded by garnet in quartz-schists from the As Sheik shear zone (Saih Hatat window, NE Oman). We observed garnet as equant, oblate and honeycomb (i.e., skeletal) shapes that document distinct fluid-related growth stages from peak-pressure to early exhumation, both occurring at eclogite facies conditions. Garnet nucleated at 2.0–2.2 GPa and 500°C–550°C after the chloritoid-out dehydration reaction. Subsequent decompression and heating (1.3–1.5 GPa, 600°C–650°C) promoted further fluid release and honeycomb garnet growth. We infer that dissolution, transport and precipitation rates primarily influenced whether garnets grew as oblate grains (i.e., as pseudomorphs on peak-pressure chloritoid grains) or newly nucleated equant grains. Honeycomb garnet was interpreted to show the permeability network that records migration and drainage of fluid. This internally produced fluid escaped from the shear zone using pre-existing grain boundaries and reaction-formed pathways. Assuming 1 km of shear zone thickness, we computed a time-integrated fluid flux of ~34 m3 m−2 for the entire duration of garnet growth. This study highlights garnet morphology as a tracer of transient fluid pathways during a burial–exhumation cycle of an eclogitic shear zone. The close connection between garnet morphology and fluids calls for a re-evaluation of similar microstructures in different tectonic settings.

Abstract Image

用石榴石显微结构跟踪剪切带脱水反应和化石流体通量
剪切带在变质作用的进、退阶段起着优先流体通道的作用。尽管如此,我们对自然环境的排水和渗透性的了解仍然有限。在挖掘出的岩石中保存的流体特征提供了对埋葬和挖掘过程中流体流动的见解。本文研究了As Sheik剪切带(Saih Hatat窗口,阿曼东北部)石英片岩中石榴石记录的流体流动过程。我们观察到石榴石呈等长、扁圆形和蜂窝状(即骨骼)形状,记录了从峰值压力到早期挖掘的不同流体相关生长阶段,两者都发生在榴辉岩相条件下。在2.0-2.2 GPa和500°C - 550°C条件下,仿氯酸盐脱水反应后石榴石成核。随后的减压和加热(1.3-1.5 GPa, 600°C - 650°C)促进了进一步的流体释放和蜂窝石榴石生长。我们推断,溶解、迁移和沉淀速率主要影响石榴石是长成扁晶(即在峰压拟绿石晶粒上的伪晶)还是新成核等晶。对蜂窝状石榴石进行了解释,显示了记录流体运移和排水的渗透网络。这种内部产生的流体利用预先存在的晶界和反应形成的通道从剪切带中逸出。假设剪切带厚度为1 km,我们计算出整个石榴石生长期间的时间积分流体通量为~34 m3 m−2。这项研究强调了石榴石形态在榴辉岩剪切带埋掘循环中作为瞬态流体路径的示踪剂。石榴石形态与流体之间的密切联系要求对不同构造背景下的相似微结构进行重新评价。
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来源期刊
CiteScore
6.60
自引率
11.80%
发文量
57
审稿时长
6-12 weeks
期刊介绍: The journal, which is published nine times a year, encompasses the entire range of metamorphic studies, from the scale of the individual crystal to that of lithospheric plates, including regional studies of metamorphic terranes, modelling of metamorphic processes, microstructural and deformation studies in relation to metamorphism, geochronology and geochemistry in metamorphic systems, the experimental study of metamorphic reactions, properties of metamorphic minerals and rocks and the economic aspects of metamorphic terranes.
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