Hydrogen production from formic acid catalyzed by NHC-Cu complexes.

IF 2.7 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2026-04-23 eCollection Date: 2026-01-01 DOI:10.3762/bjoc.22.48

Orlando Santoro, Catherine S J Cazin

引用次数: 0

Abstract

The first NHC-Cu-catalyzed decomposition of formic acid (FA) is reported. In the presence of PhSiH₃, only hydrogen is generated while CO₂ is captured by a silane species. The decomposition of an equimolar mixture of FA and an amine provided an equimolar mixture of H₂ and CO₂. The efficiency of the catalysis showed to be strongly dependent on the nature of the amine.

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NHC-Cu配合物催化甲酸制氢。

首次报道了nhc - cu催化甲酸（FA）的分解。在PhSiH3存在的情况下，只产生氢，而二氧化碳被硅烷捕获。FA和胺的等摩尔混合物的分解产生H2和CO2的等摩尔混合物。结果表明，催化效率与胺的性质密切相关。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.