Investigation of the structural, optical and electrical conductivity properties of Ga-doped ZnO nanoparticles

IF 2.8 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Hayet Mahdhi, Nesrine Haddad, Najib Ihzaz, Zouhaier Ben Ayadi
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Abstract

In this study, we report the synthesis of undoped and Ga-doped ZnO nanoparticles using the sol–gel method, with gallium concentrations ranging from 0.0 to 5.0 at%. The impact of Ga incorporation on the structural and electrical properties of the samples was systematically investigated. X-ray diffraction (XRD) analysis confirmed the formation of hexagonal wurtzite ZnO nanopowders, with crystallite sizes varying between 20 and 35 nm. Rietveld refinement further verified the hexagonal wurtzite ZnO phase within the P63mc space group. Morphological analysis indicated that the crystallites exhibit a hexagonal shape. The electrical properties were evaluated using impedance spectroscopy, revealing a strong dependence on temperature and frequency. Notably, electrical conductivity increased with Ga doping, reaching its maximum at 3.0 at% Ga content.

ga掺杂ZnO纳米粒子的结构、光学和电导率研究
在这项研究中,我们报道了使用溶胶-凝胶法合成未掺杂和掺ga的ZnO纳米粒子,镓浓度在0.0至5.0之间。系统地研究了掺入Ga对样品结构和电学性能的影响。x射线衍射(XRD)分析证实形成了六方纤锌矿ZnO纳米粉体,晶粒尺寸在20 ~ 35 nm之间。Rietveld细化进一步验证了P63mc空间群内的六方纤锌矿ZnO相。形貌分析表明,晶体呈六角形。电学性质用阻抗谱进行了评估,揭示了对温度和频率的强烈依赖。当Ga含量为%时,电导率在3.0时达到最大值。
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来源期刊
Applied Physics A
Applied Physics A 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.40%
发文量
964
审稿时长
38 days
期刊介绍: Applied Physics A publishes experimental and theoretical investigations in applied physics as regular articles, rapid communications, and invited papers. The distinguished 30-member Board of Editors reflects the interdisciplinary approach of the journal and ensures the highest quality of peer review.
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