Pd@CN-COF: a pool for palladium(0)-catalyzed reactions

IF 8.1 2区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Materials Chemistry Frontiers Pub Date : 2026-03-02 DOI:10.1039/D5QM00889A

Marcela Horáková, Milan Klikar, Jakub Halamek, Roman Bulánek, Jhonatan Rodriguez-Pereira, Veronika Čičmancová, Jan Podlesný, Eva Kolíbalová, Jan Michalička, Jan Bartáček, Patrik Pařík, Jan M. Macak and Filip Bureš

引用次数: 0

Abstract

A new cyano-substituted olefin-linked COF was synthesized and utilized as a support for palladium nanoparticles. The resulting Pd@CN-COF was demonstrated as a versatile heterogeneous catalyst in cross-coupling reactions, cyanation, and allylic substitution with the productivity exceeding the commercial homogeneous precatalyst [Pd(PPh₃)₄]. The catalytic activity of Pd@CN-COF was further evaluated in synthetically valuable transformations towards industrially, agrochemically, and pharmacologically relevant products.

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Pd@CN-COF：钯(0)催化反应池

合成了一种新型的氰基取代烯烃连接COF，并将其用作钯纳米颗粒的载体。结果表明，Pd@CN-COF在交叉偶联反应、氰化反应和烯丙基取代反应中是一种多用途的多相催化剂，其生产率超过了商品均相预催化剂[Pd(PPh3)4]。进一步评价了Pd@CN-COF在工业、农化和药理学相关产品的合成价值转化中的催化活性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Materials Chemistry Frontiers Materials Science-Materials Chemistry

CiteScore

12.00

自引率

2.90%

发文量

313

期刊介绍： Materials Chemistry Frontiers focuses on the synthesis and chemistry of exciting new materials, and the development of improved fabrication techniques. Characterisation and fundamental studies that are of broad appeal are also welcome. This is the ideal home for studies of a significant nature that further the development of organic, inorganic, composite and nano-materials.