Spontaneous Formation of a Skin Layer in Water with the Deformation of the Raman OH Band Due to the Contribution of the 3200 cm–1 Ice Component

IF 1.3 4区 物理与天体物理 Q3 PHYSICS, MULTIDISCIPLINARY
S. M. Pershin, E. V. Stepanov, D. G. Artemova, M. Ya. Grishin, P. S. Smerchanskii, G. A. Boldin
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引用次数: 0

Abstract

The spontaneous formation of a skin layer of distilled water, up to 3 mm thick, with new properties over ~4 h has been discovered. Deformation of the Raman OH band due to the contribution of the ice component (~3200 cm–1), a decrease in the elastic scattering coefficient and its fluctuations, and a ~20% increase in the height of the meniscus in capillaries have been detected. The recovery of the layer after enrichment with air due to mixing indicates the stability of the formation of ice-like structures. The filling of the ice-like structures with H2O monomers, which form hydrogen bonds with SiO2 molecules of the capillary walls, increases their wettability and, consequently, the height of the meniscus.

Abstract Image

由于3200 cm-1冰分量的贡献,在水中自发形成具有拉曼OH带变形的皮肤层
蒸馏水自发形成一层皮肤,厚度达3mm,在约4小时内具有新特性。由于冰分量(~3200 cm-1)的贡献,拉曼OH带发生了变形,弹性散射系数及其波动减小,毛细血管中半月板高度增加了~20%。由于混合而使空气富集后,层的恢复表明了冰状结构形成的稳定性。用H2O单体填充冰状结构,与毛细血管壁上的SiO2分子形成氢键,增加了它们的润湿性,从而提高了半月板的高度。
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来源期刊
JETP Letters
JETP Letters 物理-物理:综合
CiteScore
2.40
自引率
30.80%
发文量
164
审稿时长
3-6 weeks
期刊介绍: All topics of experimental and theoretical physics including gravitation, field theory, elementary particles and nuclei, plasma, nonlinear phenomena, condensed matter, superconductivity, superfluidity, lasers, and surfaces.
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