Study of PEG/Biochar Cementitious Cold-Bonded Aggregate for Thermal Energy Storage.

Abstract

The incorporation of phase change materials in concrete is a practical strategy that holds great promise for enhancing the energy efficiency of buildings and reducing CO₂ emissions. However, the direct contact between phase change materials and cement interferes with the cement hydration reaction, leading to a significant reduction in the mechanical strength of cementitious composites. To encapsulate polyethylene glycol and prevent leakage, this study developed a shape-stabilized phase change aggregate via the cold-bonding method and the vacuum impregnation method. The nanoscale pore structure of the aggregate was regulated by adjusting the biochar content to enhance the phase-change material loading capacity. The phase change aggregate was characterized by indicators including crushing strength and water absorption. Meanwhile, its microstructure, the correlations between nano-sized hydration products, chemical compatibility, and phase change properties were analyzed. The fabricated phase change aggregate has a crushing strength of over 5 MPa, latent heat of 42.84 J/g, and phase change temperature of 29.17 °C while also exhibiting good mechanical properties and thermal energy storage performance. The compressive strength of phase change concrete can meet the strength requirements for structural building material. Moreover, phase change aggregate contributed to reduced CO₂ emissions during service, with favorable economic and low-carbon benefits over its service life, demonstrating good performance in both economic efficiency and CO₂ emission reduction.